Buckybowls: Corannulene and Its Derivatives.

作者: Xu Li , Feiyu Kang , Michio Inagaki

DOI: 10.1002/SMLL.201503950

关键词: CorannuleneComputational chemistryResearch groupsMoleculeHydrogen storageChemistryHost–guest chemistry

摘要: Corannulene, a kind of bowl like polycyclic aromatic hydrocarbon (PAH), whose molecule is composed central pentagon and five closely adjacent hexagons on the pentagon's sides, has received great scientific interest among research groups. In this review, syntheses, characteristic structure properties corannulene are clarified, as well its derivatives with different substituted groups, fused derivatives, metal complex, for host guest chemistry. On basis reviewing applications together potential in hydrogen storage lithium were highlighted prospected.

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