Synthesis and characterization of novel polyvalent organoiodine compounds

作者: Bindu V. Meprathu , John D. Protasiewicz

DOI: 10.3998/ARK.5550190.0004.610

关键词: NitreneBenzeneIodobenzeneChemistryOrganic chemistry

摘要: Synthesis and characterization of soluble analogues iodosylbenzene PhIO (tosyliminoiodo)benzene PhINTs are reported. The syntheses 4-trifluoromethyl-2-(tertbutylsulfonyl)iodosylbenzene (3) 4-trifluoromethyl-2-(tert-butylsulfonyl)(tosylimino)iodobenzene (4) increase the repertoire available organoiodine(III) based oxo- nitrene precursors. We also report synthesis a new organoiodine(V) compound, 4-trifluoromethyl-2-(tert-butylsulfonyl)iodylbenzene.

参考文章(1)
Anastasios Varvoglis, Hypervalent iodine in organic synthesis ,(1996)