作者: Bindu V. Meprathu , John D. Protasiewicz
DOI: 10.3998/ARK.5550190.0004.610
关键词: Nitrene 、 Benzene 、 Iodobenzene 、 Chemistry 、 Organic chemistry
摘要: Synthesis and characterization of soluble analogues iodosylbenzene PhIO (tosyliminoiodo)benzene PhINTs are reported. The syntheses 4-trifluoromethyl-2-(tertbutylsulfonyl)iodosylbenzene (3) 4-trifluoromethyl-2-(tert-butylsulfonyl)(tosylimino)iodobenzene (4) increase the repertoire available organoiodine(III) based oxo- nitrene precursors. We also report synthesis a new organoiodine(V) compound, 4-trifluoromethyl-2-(tert-butylsulfonyl)iodylbenzene.