作者: Douglas Henderson , Lesser Blum , Joel L. Lebowitz
DOI: 10.1016/S0022-0728(79)80459-3
关键词: Field (physics) 、 Value (mathematics) 、 Limit (mathematics) 、 Charge (physics) 、 Exact formula 、 Hard spheres 、 Classical mechanics 、 Physics
摘要: An exact formula for the contact value of density a system charged hard spheres near wall is obtained by means general statistical mechanical argument. In addition, charge profile in limit large field obtained. Comparison with corresponding expressions Poisson-Boltzmann theory Gouy and Chapman shows that these latter become fields, independent spheres.