An exact formula for the contact value of the density profile of a system of charged hard spheres near a charged wall

作者: Douglas Henderson , Lesser Blum , Joel L. Lebowitz

DOI: 10.1016/S0022-0728(79)80459-3

关键词: Field (physics)Value (mathematics)Limit (mathematics)Charge (physics)Exact formulaHard spheresClassical mechanicsPhysics

摘要: An exact formula for the contact value of density a system charged hard spheres near wall is obtained by means general statistical mechanical argument. In addition, charge profile in limit large field obtained. Comparison with corresponding expressions Poisson-Boltzmann theory Gouy and Chapman shows that these latter become fields, independent spheres.

参考文章(3)
Douglas Henderson, Lesser Blum, Some exact results and the application of the mean spherical approximation to charged hard spheres near a charged hard wall Journal of Chemical Physics. ,vol. 69, pp. 5441- 5449 ,(1978) , 10.1063/1.436535
David Leonard Chapman, LI. A contribution to the theory of electrocapillarity Philosophical Magazine Series 1. ,vol. 25, pp. 475- 481 ,(1913) , 10.1080/14786440408634187
Douglas Henderson, Lesser Blum, William R. Smith, Application of the hypernetted chain approximation to the electric double layer at a charged planar interface Chemical Physics Letters. ,vol. 63, pp. 381- 383 ,(1979) , 10.1016/0009-2614(79)87041-4