The mixed alkali effect in the Na2OCs2OSiO2 glasses
作者： R. Terai
DOI: 10.1016/0022-3093(71)90051-2
关键词: Bond strength 、 Electrical resistivity and conductivity 、 Inorganic chemistry 、 Alkali metal 、 Sodium 、 Activation energy 、 Ion 、 Dealkalization 、 Mixed alkali effect 、 Chemistry 、 Materials Chemistry 、 Electronic, Optical and Magnetic Materials 、 Condensed matter physics 、 Ceramics and Composites
摘要: Abstract As an approach to the mixed alkali effect in glass, self-diffusion coefficients of sodium and cesium ions Na 2 OCs OSiO glasses were measured at temperatures 350–550°C. Electrical conductivity transport number for also measured. The substitution glass by different caused mobility each ion decrease pronouncedly activation energy migration increase rapidly. was attributed alkali-oxygen bond strength resulting from presence two kinds ions. This is related expectation that activity decreases when are mixed.
harvard.edu
elsevier.com
sci-hub.se 参考文章(15)
Milton Blander, Some Calculations for a One‐Dimensional Salt Mixture The Journal of Chemical Physics. ,vol. 34, pp. 697- 698 ,(1961) , 10.1063/1.1701026
R. D. Shannon, C. T. Prewitt, Effective ionic radii in oxides and fluorides Acta Crystallographica Section B Structural Crystallography and Crystal Chemistry. ,vol. 25, pp. 925- 946 ,(1969) , 10.1107/S0567740869003220
John Lumsden, Thermodynamics of molten mixtures of alkali-metal halides Discussions of the Faraday Society. ,vol. 32, pp. 138- 146 ,(1961) , 10.1039/DF9613200138
O. J. Kleppa, L. S. Hersh, Heats of Mixing in Liquid Alkali Nitrate Systems The Journal of Chemical Physics. ,vol. 34, pp. 351- 358 ,(1961) , 10.1063/1.1700955
O. J. Kleppa, A NEW TWIN HIGH-TEMPERATURE REACTION CALORIMETER. THE HEATS OF MIXING IN LIQUID SODIUM-POTASSIUM NITRATES The Journal of Physical Chemistry. ,vol. 64, pp. 1937- 1940 ,(1960) , 10.1021/J100841A032
R. J. CHARLES, The Mixed Alkali Effect in Glasses Journal of the American Ceramic Society. ,vol. 48, pp. 432- 433 ,(1965) , 10.1111/J.1151-2916.1965.TB14784.X
Michael G. Clark, Algebraic Symmetry and Quantum Secular Equations The Journal of Chemical Physics. ,vol. 54, pp. 697- 702 ,(1971) , 10.1063/1.1674898
GEORGE W. MOREY, THE CONSTITUTION OF GLASS Journal of the American Ceramic Society. ,vol. 17, pp. 315- 328 ,(1934) , 10.1111/J.1151-2916.1934.TB19332.X
JAMES E. SHELBY, DELBERT E. DAY, Mechanical Relaxations in Mixed Alkali Silicate Glasses: II, Discussion Journal of the American Ceramic Society. ,vol. 53, pp. 182- 187 ,(1970) , 10.1111/J.1151-2916.1970.TB12067.X
J. M. Stevels, The Electrical Properties of Glass Handbuch der Physik. ,vol. 4, pp. 350- 391 ,(1957) , 10.1007/978-3-642-45859-0_3