Poly(vinyl pyrrolidone) matrix and SiO2, Al2O3, SnO2, ZnO, and TiO2 nanofillers comprise biodegradable nanocomposites of controllable optical properties for optoelectronic applications
作者： Priyanka Dhatarwal , R.J. Sengwa
DOI: 10.1016/J.IJLEO.2021.167215
关键词: Nanomaterials 、 Band gap 、 Oxide 、 Nanocomposite 、 Materials science 、 Optical conductivity 、 Titanium dioxide 、 Tin oxide 、 Optoelectronics 、 Polymer nanocomposite
摘要: Abstract This paper reports the detailed ultraviolet-visible (UV-Vis) range absorbance, transmittance, and reflectance spectra, various optical parameters (viz. energy band gaps, Urbach energy, refractive index, extinction coefficient, complex dielectric permittivity, conductivity) of polymer nanocomposite (PNC) films comprising biodegradable poly(vinyl pyrrolidone) (PVP) matrix different oxide nanofillers (i.e., silica (SiO2), alumina (Al2O3), tin (SnO2), zinc (ZnO), titanium dioxide (TiO2)). The effects these their concentrations (1–5 wt%) on properties nanocomposites were systematically explored comparatively demonstrated, especially with consideration behaviour wide gap semiconductor nanomaterials (SnO2, ZnO, TiO2). results confirmed that SiO2 Al2O3 nanoparticles containing PNCs found controllable in a narrow by variation filler concentration, whereas can be tuned for SnO2, TiO2 loaded PVP matrix-based PNC films. multifunctionalities revealed appropriateness development regulator, UV-shielder, light diffuser, photo-sensor, detector-type optoelectronic devices.
sci-hub.st 参考文章(45)
Mirela Teodorescu, Maria Bercea, Poly(vinylpyrrolidone) – A Versatile Polymer for Biomedical and Beyond Medical Applications Polymer-plastics Technology and Engineering. ,vol. 54, pp. 923- 943 ,(2015) , 10.1080/03602559.2014.979506
A.M. El Sayed, Ali Ibrahim, Structural and optical characterizations of spin coated cobalt-doped cadmium oxide nanostructured thin films Materials Science in Semiconductor Processing. ,vol. 26, pp. 320- 328 ,(2014) , 10.1016/J.MSSP.2014.05.019
Yifan Zhang, Mira Park, Hak-Yong Kim, Mohamed El-Newehy, Kyong Yop Rhee, Soo-Jin Park, Effect of TiO2 on photocatalytic activity of polyvinylpyrrolidone fabricated via electrospinning Composites Part B-engineering. ,vol. 80, pp. 355- 360 ,(2015) , 10.1016/J.COMPOSITESB.2015.05.040
A.M. Abdelghany, E.M. Abdelrazek, S.I. Badr, M.A. Morsi, Effect of gamma-irradiation on (PEO/PVP)/Au nanocomposite: Materials for electrochemical and optical applications Materials & Design. ,vol. 97, pp. 532- 543 ,(2016) , 10.1016/J.MATDES.2016.02.082
Shadpour Mallakpour, Mina Naghdi, Fabrication and characterization of novel polyvinylpyrrolidone nanocomposites having SiO2 nanoparticles modified with citric acid and L(+)-ascorbic acid Polymer. ,vol. 90, pp. 295- 301 ,(2016) , 10.1016/J.POLYMER.2016.03.029
Michael Dahl, Yiding Liu, Yadong Yin, Composite Titanium Dioxide Nanomaterials Chemical Reviews. ,vol. 114, pp. 9853- 9889 ,(2014) , 10.1021/CR400634P
Elena O. Filatova, Aleksei S. Konashuk, Interpretation of the Changing the Band Gap of Al2O3 Depending on Its Crystalline Form: Connection with Different Local Symmetries Journal of Physical Chemistry C. ,vol. 119, pp. 20755- 20761 ,(2015) , 10.1021/ACS.JPCC.5B06843
W. Suthabanditpong, C. Takai, M. Fuji, R. Buntem, T. Shirai, Improved optical properties of silica/UV-cured polymer composite films made of hollow silica nanoparticles with a hierarchical structure for light diffuser film applications Physical Chemistry Chemical Physics. ,vol. 18, pp. 16293- 16301 ,(2016) , 10.1039/C6CP01005A
Tomasz Tański, Wiktor Matysiak, Łukasz Krzemiński, Paweł Jarka, Klaudiusz Gołombek, None, Optical properties of thin fibrous PVP/SiO 2 composite mats prepared via the sol-gel and electrospinning methods Applied Surface Science. ,vol. 424, pp. 184- 189 ,(2017) , 10.1016/J.APSUSC.2017.02.258
Jing Zhao, Yanyang Yang, Yu Li, Liang Zhao, Hao Wang, Guolin Song, Guoyi Tang, Microencapsulated phase change materials with TiO2-doped PMMA shell for thermal energy storage and UV-shielding Solar Energy Materials and Solar Cells. ,vol. 168, pp. 62- 68 ,(2017) , 10.1016/J.SOLMAT.2017.04.014