Characterization and catalytic performance of mesoporous molecular sieves Al-MCM-41 materials
作者： X. Chen , L. Huang , G. Ding , Q. Li
关键词: Molecular sieve 、 Thermogravimetric analysis 、 Acid strength 、 Mesoporous organosilica 、 Fluid catalytic cracking 、 Aluminium 、 Mesoporous material 、 Chemistry 、 MCM-41 、 Inorganic chemistry
摘要: Mesoporous Al-MCM-41 materials of different Si/Al ratios have been synthesized and characterized by X-ray powder diffraction, 27Al 29Si MAS NMR, differential thermogravimetric analysis, N2 adsorption measurements, FT-IR catalytic cracking alkanes. The experimental results show that the incorporation aluminium into framework MCM-41 has a great effect on degree long-distance order, surface acidities mesoporous structures materials. With increase content, amounts tetrahedral acid sites samples increase, but strength decreases. exhibit high activity for n-C160 good selectivity producing low carbon alkylenes, particularly i-C4=.
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sci-hub.se 参考文章(10)
Ralf Schmidt, Duncan Akporiayea, Michael Stöcker, Ole Henrik Ellestad, Synthesis of Al-Containing MCM-41 Materials: Template Interaction and Removal Studies in Surface Science and Catalysis. ,vol. 84, pp. 61- 68 ,(1994) , 10.1016/S0167-2991(08)64097-5
M. Janicke, D. Kumar, G.D. Stucky, B.F. Chmelka, Aluminum Incorporation in Mesoporous Molecular Sieves Studies in Surface Science and Catalysis. ,vol. 84, pp. 243- 250 ,(1994) , 10.1016/S0167-2991(08)64120-8
J. S. Beck, J. C. Vartuli, W. J. Roth, M. E. Leonowicz, C. T. Kresge, K. D. Schmitt, C. T. W. Chu, D. H. Olson, E. W. Sheppard, S. B. McCullen, J. B. Higgins, J. L. Schlenker, A new family of mesoporous molecular sieves prepared with liquid crystal templates Journal of the American Chemical Society. ,vol. 114, pp. 10834- 10843 ,(1992) , 10.1021/JA00053A020
Robert Mokaya, William Jones, Zhaohua Luan, Maria D. Alba, Jacek Klinowski, Acidity and catalytic activity of the mesoporous aluminosilicate molecular sieve MCM-41 Catalysis Letters. ,vol. 37, pp. 113- 120 ,(1996) , 10.1007/BF00813528
A. Corma, M.S. Grande, V. Gonzalez-Alfaro, A.V. Orchilles, Cracking Activity and Hydrothermal Stability of MCM-41 and Its Comparison with Amorphous Silica-Alumina and a USY Zeolite Journal of Catalysis. ,vol. 159, pp. 375- 382 ,(1996) , 10.1006/JCAT.1996.0100
Peter T. Tanev, Malama Chibwe, Thomas J. Pinnavaia, Titanium-containing mesoporous molecular sieves for catalytic oxidation of aromatic compounds Nature. ,vol. 368, pp. 321- 323 ,(1994) , 10.1038/368321A0
C. T. Kresge, M. E. Leonowicz, W. J. Roth, J. C. Vartuli, J. S. Beck, Ordered mesoporous molecular sieves synthesized by a liquid-crystal template mechanism Nature. ,vol. 359, pp. 710- 712 ,(1992) , 10.1038/359710A0
K. R. Kloetstra, H. W. Zandbergen, H. van Bekkum, MCM-41 type materials with low Si/Al ratios Catalysis Letters. ,vol. 33, pp. 157- 163 ,(1995) , 10.1007/BF00817055
Ramesh B. Borade, Abraham Clearfield, Synthesis of aluminum rich MCM-41 Catalysis Letters. ,vol. 31, pp. 267- 272 ,(1995) , 10.1007/BF00808839
A. Corma, A. Martinez, V. Martinezsoria, J.B. Monton, Hydrocracking of Vacuum Gasoil on the Novel Mesoporous MCM-41 Aluminosilicate Catalyst Journal of Catalysis. ,vol. 153, pp. 25- 31 ,(1995) , 10.1006/JCAT.1995.1104