Synthesis, Characterization and Electrocatalysis of Phenyl-Functionalized Diiron Propanediselenolato Complexes

作者: Chang-Gong Li , Shu-Ke Jing , Feng Xue , Yong Zhu , Mao-Jin Cui

DOI: 10.1007/S10876-015-0873-Y

关键词: CatalysisDiphenylphosphineOxidative additionEthyleneCrystal structureVoltammetryTriphenylphosphineChemistryOrganic chemistryElectrocatalystMedicinal chemistry

摘要: Reaction of 2-phenyl-1,3-dibromopropane with in situ generated Na 2 Se 2 gave 4-phenyl-1,2-diselenolancyclopentane, which subsequently underwent the oxidative addition with Fe 3 …

参考文章(48)
Mohammad K. Harb, Ahmad Daraosheh, Helmar Görls, Elliott R. Smith, G. Joel Meyer, Matthew T. Swenson, Takahiro Sakamoto, Richard S. Glass, Dennis L. Lichtenberger, Dennis H. Evans, Mohammad El-khateeb, Wolfgang Weigand, Effects of Alkane Linker Length and Chalcogen Character in [FeFe]-Hydrogenase Inspired Compounds Heteroatom Chemistry. ,vol. 25, pp. 592- 606 ,(2014) , 10.1002/HC.21216
Daesung Chong, Irene P. Georgakaki, Rosario Mejia-Rodriguez, Jean Sanabria-Chinchilla, Manuel P. Soriaga, Marcetta Y. Darensbourg, Electrocatalysis of hydrogen production by active site analogues of the iron hydrogenase enzyme: structure/function relationships Dalton Transactions. pp. 4158- 4163 ,(2003) , 10.1039/B304283A
Yvain Nicolet, Claudine Piras, Pierre Legrand, Claude E Hatchikian, Juan C Fontecilla-Camps, Desulfovibrio desulfuricans iron hydrogenase: the structure shows unusual coordination to an active site Fe binuclear center. Structure. ,vol. 7, pp. 13- 23 ,(1999) , 10.1016/S0969-2126(99)80005-7
Li-Cheng Song, Bin Gai, Hu-Ting Wang, Qing-Mei Hu, Synthesis, characterization and electrocatalysis of diiron propanediselenolate derivatives as the active site models of [FeFe]-hydrogenases. Journal of Inorganic Biochemistry. ,vol. 103, pp. 805- 812 ,(2009) , 10.1016/J.JINORGBIO.2009.02.002
Patrick C Hallenbeck, John R Benemann, Biological hydrogen production; fundamentals and limiting processes International Journal of Hydrogen Energy. ,vol. 27, pp. 1185- 1193 ,(2002) , 10.1016/S0360-3199(02)00131-3
Chang-Gong Li, Yong-Fang Li, Jing-Yan Shang, Tian-Jun Lou, Synthesis and electrochemistry of phenyl-functionalized diiron propanedithiolate complexes with bidentate phosphine ligands Transition Metal Chemistry. ,vol. 39, pp. 373- 378 ,(2014) , 10.1007/S11243-014-9810-4
Frédéric Gloaguen, Thomas B. Rauchfuss, Small molecule mimics of hydrogenases: hydrides and redox Chemical Society Reviews. ,vol. 38, pp. 100- 108 ,(2009) , 10.1039/B801796B
Yvain Nicolet, Christine Cavazza, J.C. Fontecilla-Camps, Fe-only hydrogenases: structure, function and evolution. Journal of Inorganic Biochemistry. ,vol. 91, pp. 1- 8 ,(2002) , 10.1016/S0162-0134(02)00392-6