Isolation of a Bimetallic Cobalt(III) Nitride and Examination of Its Hydrogen Atom Abstraction Chemistry and Reactivity toward H2.
作者： Debabrata Sengupta , Christian Sandoval-Pauker , Emily Schueller , Angela M. Encerrado-Manriquez , Alejandro Metta-Magaña
DOI: 10.1021/JACS.0C00291
关键词: Bimetallic strip 、 Hydrogen atom abstraction 、 Polymer chemistry 、 Reactivity (chemistry) 、 Nitride 、 Azide 、 Chemistry 、 Photodissociation 、 Cobalt
摘要: Room temperature photolysis of the bis(azide)cobaltate(II) complex [Na(THF)x][(ketguan)Co(N3)2] (ketguan = [(tBu2CN)C(NDipp)2]−, Dipp 2,6-diisopropylphenyl) (3a) in THF cleanly forms binuclea...
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G. Schaftenaar, J.H. Noordik, Molden: a pre- and post-processing program for molecular and electronic structures. Journal of Computer-aided Molecular Design. ,vol. 14, pp. 123- 134 ,(2000) , 10.1023/A:1008193805436
G.W.A. Fowles, D.A. Rice, R.A. Walton, The donor properties of simple ethers—II[1]: Complexes of manganese(II), iron(II), cobalt(II) and nickel(II) halides with tetrahydrofuran and 1,2-dimethoxyethane Journal of Inorganic and Nuclear Chemistry. ,vol. 31, pp. 3119- 3131 ,(1969) , 10.1016/0022-1902(69)80095-3
Róbert Izsák, Andreas Hansen, Frank Neese, The resolution of identity and chain of spheres approximations for the LPNO-CCSD singles Fock term Molecular Physics. ,vol. 110, pp. 2413- 2417 ,(2012) , 10.1080/00268976.2012.687466
Florian Weigend, Reinhart Ahlrichs, Balanced basis sets of split valence, triple zeta valence and quadruple zeta valence quality for H to Rn: Design and assessment of accuracy Physical Chemistry Chemical Physics. ,vol. 7, pp. 3297- 3305 ,(2005) , 10.1039/B508541A
Simone Kossmann, Frank Neese, Efficient Structure Optimization with Second-Order Many-Body Perturbation Theory: The RIJCOSX-MP2 Method. Journal of Chemical Theory and Computation. ,vol. 6, pp. 2325- 2338 ,(2010) , 10.1021/CT100199K
Xile Hu, Karsten Meyer, Terminal cobalt(III) imido complexes supported by tris(carbene) ligands: imido insertion into the cobalt-carbene bond. Journal of the American Chemical Society. ,vol. 126, pp. 16322- 16323 ,(2004) , 10.1021/JA044271B
John P. Perdew, Matthias Ernzerhof, Kieron Burke, Rationale for mixing exact exchange with density functional approximations Journal of Chemical Physics. ,vol. 105, pp. 9982- 9985 ,(1996) , 10.1063/1.472933
Gordon A. Bain, John F. Berry, Diamagnetic Corrections and Pascal's Constants Journal of Chemical Education. ,vol. 85, pp. 532- 536 ,(2008) , 10.1021/ED085P532
Oleg V. Dolomanov, Luc J. Bourhis, Richard J. Gildea, Judith A. K. Howard, Horst Puschmann, OLEX2: a complete structure solution, refinement and analysis program Journal of Applied Crystallography. ,vol. 42, pp. 339- 341 ,(2009) , 10.1107/S0021889808042726
Frank Neese, The ORCA program system Wiley Interdisciplinary Reviews: Computational Molecular Science. ,vol. 2, pp. 73- 78 ,(2012) , 10.1002/WCMS.81