Rhodium-Katalysatoren für die enantioselektive Hydrosilylierung-ein neues Konzept zur Entwicklung asymmetrischer Katalysatoren
作者： Henri Brunner
关键词: Cyclopentadiene 、 Enantioselective synthesis 、 Chemistry 、 Stereochemistry 、 Acetophenone 、 Diastereomer 、 Cyclooctadiene 、 Hydrosilylation 、 Stereoselectivity
摘要: Nach einem uberblick uber die asymmetrische Hydrierung prochiraler Olefine mit ubergangsmetall/Phosphan-Katalysatoren wird das Problem der Chiralitatsubertragung von den optisch aktiven Liganden des Katalysators auf Substrat diskutiert. Es ein neues Konzept fur diese vorgestellt; Konformationsanalyse Modellverbindungen sowie Entwicklung Katalysatoren enantioselektive Hydrosilylierung demonstrieren Nutzlichkeit dieses Konzepts.
sci-hub.se 参考文章(89)
Henri Brunner, Optical induction in organo-transition-metal compounds and asymmetric catalysis Accounts of Chemical Research. ,vol. 10, pp. 250- 257 ,(1979) , 10.1021/AR50139A005
M. D. Fryzuk, B. Bosnich, Asymmetric synthesis. An asymmetric homogeneous hydrogenation catalyst which breeds its own chirality Journal of the American Chemical Society. ,vol. 100, pp. 5491- 5494 ,(1978) , 10.1021/JA00485A037
Henri Brunner, Devendra K. Rastogi, Optically active transition-metal complexes. 65. Conformational analysis in diastereoisomer equilibriums of square-pyramidal dicarbonylcyclopentadienylmolybdenum-pyridine-2-carbaldimine complexes using the Ruch Ugi rules Inorganic Chemistry. ,vol. 19, pp. 891- 895 ,(1980) , 10.1021/IC50206A020
Yoshihiko Saito, Inorganic Molecular Dissymmetry Springer Berlin Heidelberg. ,(1979) , 10.1007/978-3-642-67181-4
László Markó, József Bakos, Substrates and Phosphorus Ligands Used in Asymmetric Homogeneous Hydrogenations Catalysed by Rhodium Complexes Aspects of Homogeneous Catalysis. ,vol. 12, pp. 145- 202 ,(1981) , 10.1007/978-94-009-8371-7_4
Iwao Ojima, Homogeneous Asymmetric Hydrogenation and Hydrosilylation of Keto Esters Catalyzed by Chiral Rhodium Complexes Springer, Boston, MA. pp. 181- 206 ,(1978) , 10.1007/978-1-4615-7041-7_13
H.B. Kagan, Asymmetric Synthesis using Organometallic Catalysts Comprehensive Organometallic Chemistry. ,vol. 53, pp. 463- 498 ,(1982) , 10.1016/B978-008046518-0.00112-4
Iwao Ojima, Keiji Yamamoto, Makoto Kumada, Asymmetric Hydrosilylation by Means of Homogeneous Catalysts with Chiral Ligands ChemInform. ,vol. 9, pp. 185- 228 ,(1977) , 10.1007/978-94-010-1199-0_3
Piero Pino, Giambattista Consiglio, Homogeneous Asymmetric Catalysis by Transition Metal Complexes Fundamental Research in Homogeneous Catalysis. ,vol. 11, pp. 519- 536 ,(1979) , 10.1007/978-1-4613-2958-9_35
Henri Brunner, Chiral Metal Atoms in Optically Active Organo-Transition-Metal Compounds ChemInform. ,vol. 18, pp. 151- 206 ,(1980) , 10.1016/S0065-3055(08)60308-1