Synthesis, structure and spectroscopic properties of bis(triphenylphosphane)iminium (phenylacetylido)(cyanido)aurate(I) monoacetone monohydrate, (PPN)[Au(CN)(CCC6H5)]·H2O·(CH3)2CO and bis(triphenylphosphane)iminium (t-butylacetylido)(cyanido)aurate(I) monohydrate, (PPN)[Au(CN)(CCC4H9)]·H2O
作者： Ali Alsalme , Mohammed Jaafar , Xue Liu , Fabian Dielmann , F. Ekkehardt Hahn
DOI: 10.1016/J.POLY.2014.12.022
关键词: Bond length 、 Coinage metals 、 Photochemistry 、 Acetylide 、 Molecule 、 Chemistry 、 Hydrogen bond 、 Excited state 、 Crystallography 、 Iminium 、 Luminescence
摘要: Abstract Two new compounds containing the (acetylido)(cyanido)aurate(I) anion are reported. Their solid-state structures with monocation PPN, bis(triphenylphosphane)iminium, reported as a product water molecule and an acetone for phenylacetylide compound, monohydrate in case of t -butylacetylide compound. The gold atom is linearly coordinated normal Au–C bonds both cases (1.97–1.99 A). Hydrogen bond chains found from N to acetone, H D⋯A contact distances 2.92 A (O⋯O) 3.01 A (O⋯N) PPN cation has lengths no short contacts other atoms lattice observed. luminescence properties have been measured solid powders. compound shows medium strength emission two peaks at 431 454 nm when excited 310 nm. excitation spectra monitored 454 nm, respectively, show similar broad band maximum 310–317 nm. Surprisingly, displays negligible luminescence.
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Andrea Barbieri, Gianluca Accorsi, Nicola Armaroli, Luminescent complexes beyond the platinum group: the d10 avenue Chemical Communications. pp. 2185- 2193 ,(2008) , 10.1039/B716650H
Lukáš Palatinus, Siriyara Jagannatha Prathapa, Sander van Smaalen, EDMA: a computer program for topological analysis of discrete electron densities Journal of Applied Crystallography. ,vol. 45, pp. 575- 580 ,(2012) , 10.1107/S0021889812016068
Kenta Imoto, Miho Takemura, Hiroko Tokoro, Shin-ichi Ohkoshi, A Cyano‐Bridged Vanadium–Niobium Bimetal Assembly Exhibiting a High Curie Temperature of 210 K European Journal of Inorganic Chemistry. ,vol. 2012, pp. 2649- 2652 ,(2012) , 10.1002/EJIC.201101219
Howard H Patterson, Sofian M Kanan, Mohammad A Omary, Luminescent homoatomic exciplexes in dicyanoargenate(I) ions doped in alkali halide crystals. ‘Exciplex tuning’ by site-selective excitation and variation of the dopant concentration Coordination Chemistry Reviews. ,vol. 208, pp. 227- 241 ,(2000) , 10.1016/S0010-8545(00)00294-0
Mohammed Jaafar, Andrej Pevec, Sebastiaan Akerboom, Ali Alsalme, Khalid Al-Farhan, Mohamed Ghazzali, Jan Reedijk, Synthesis, structure and spectroscopic properties of two new cyanido-bridged trinuclear 9-atom molecular Ag N C Cu N C Au C N assembly of formula [AgCuAu(CN) 3 (PPh 3 ) 5 ](H 2 O) 2 and a dinuclear gold–copper one-dimensional coordination polymer of formula [AuCu(CN) 2 (PPh 3 ) 2 ](H 2 O) 2 Inorganica Chimica Acta. ,vol. 423, pp. 233- 237 ,(2014) , 10.1016/J.ICA.2014.08.017
Jun Xia, Tian-Tian Li, Xiao-Qinq Zhao, Jun-Fu Wei, Cyano-bridged heterometallic complexes directed by binuclear copper units Journal of Coordination Chemistry. ,vol. 66, pp. 539- 550 ,(2013) , 10.1080/00958972.2012.763118
Yong-Yue Lin, Siu-Wai Lai, Chi-Ming Che, Fu, Zhong-Yuan Zhou, Nianyong Zhu, Structural variations and spectroscopic properties of luminescent mono- and multinuclear silver(I) and copper(I) complexes bearing phosphine and cyanide ligands Inorganic Chemistry. ,vol. 44, pp. 1511- 1524 ,(2005) , 10.1021/IC048876K
Craig A. Bayse, Jasprina L. Ming, Kayla M. Miller, Shannon M. McCollough, Robert D. Pike, Photoluminescence of silver(I) and gold(I) cyanide 1D coordination polymers Inorganica Chimica Acta. ,vol. 375, pp. 47- 52 ,(2011) , 10.1016/J.ICA.2011.04.020
Mohamed Ghazzali, Mohammed H. Jaafar, Khalid Al-Farhan, Sebastiaan Akerboom, Jan Reedijk, Synthesis, structure and luminescence of new dinuclear cyanido-bridged AgI–AuI one-dimensional coordination polymer Inorganic Chemistry Communications. ,vol. 20, pp. 188- 190 ,(2012) , 10.1016/J.INOCHE.2012.03.005
Mohamed Ghazzali, Mohammed H. Jaafar, Sebastiaan Akerboom, Ali Alsalme, Khalid Al-Farhan, Jan Reedijk, A series of bimetallic chain coordination polymers bearing [Ag(PPh3)2] chromophores: Synthesis, structure and luminescence Inorganic Chemistry Communications. ,vol. 36, pp. 18- 21 ,(2013) , 10.1016/J.INOCHE.2013.07.020