Silyl and Stannyl Derivatives of Organocopper Compounds

作者: Francisco J. Pulido , Asunción Barbero

DOI: 10.1002/9780470682531.PAT0449

关键词: SilylationElectrophileReactivity (chemistry)Organic chemistryChemistry

摘要: 1 Introduction 2 Silylcuprates 3 Stannylcuprates Keywords: silyl and stannyl derivatives of organocopper compounds; organocuprate chemistry, emerging as fundamental topics in organic chemistry; heteroatomcuprates containing Group IVA ligands; silylcuprates - interest silylcuprates high reactivity toward electrophiles; structure silylcuprates; synthesis allylsilanes from α,β-unsaturated esters; success cyclization depending on relative silylcuprate; stannylcuprates preparation stannylcuprates

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