Aldehyde and Ketone Functions Further Substituted on Oxygen
作者： D.A. Selden , D.M. Hodgson
DOI: 10.1016/B0-08-044655-8/00052-0
关键词: Cycloaddition 、 Epoxide 、 Intramolecular force 、 Ylide 、 Aldehyde 、 Ketone 、 Elimination reaction 、 Organic chemistry 、 Ozonolysis 、 Chemistry
摘要: This chapter covers the developments in carbonyl ylide and oxide chemistry from 1995 to 2003. The major methods of formation ylides are discussed: epoxide ring opening, interaction carbenes with compounds, cycloreversion reactions, elimination reactions. Also included recently developed for enantioselective generation reaction ylides, particularly inter- intramolecular cycloaddition Carbonyl ozonolysis alkenes alkynes, molecular oxygen, is examined reference mechanistic studies, its importance atmospheric chemistry, synthetic uses oxides.
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