Synthesis and Characterization of 3,4,5‐Triamino‐1,2,4‐triazolium and 1‐Methyl‐3,4,5‐triamino‐1,2,4‐triazolium Iodides
作者： Chaza Darwich , Konstantin Karaghiosoff , Thomas M. Klapötke , Carles Miró Sabaté
关键词: Analytical chemistry 、 Polymer chemistry 、 Iodide 、 Characterization (materials science) 、 Crystal structure 、 Yield (chemistry) 、 Infrared spectroscopy 、 Chemistry 、 Nuclear magnetic resonance spectroscopy 、 Raman spectroscopy
摘要: 3,4,5-Triamino-1,2,4-triazolium iodide (1) was obtained in good yield and purity characterized using vibrational (IR, Raman) multinuclear NMR spectroscopy (1H, 13C, 15N), EA, MS, DSC, X-ray crystallography. The compound synthesized by two different methods rendering polymorphs (α β) as proved measurements, DSC. 1-Methyl-3,4,5-triamino-1,2,4-triazolium (2) reaction of guanazine with methyliodide fully the same techniques mentioned above. Both compounds showed to be suitable starting materials for synthesis guanazinium salts energetic interest.
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