Ca2+ Reactivity in the Gas Phase. Bonding, Catalytic Effects and Coulomb Explosions
作者： Inés Corral , Cristina Trujillo , Jean-Yves Salpin , Manuel Yáñez
DOI: 10.1007/978-90-481-3034-4_1
关键词: Coulomb 、 Catalysis 、 Chemical physics 、 Electron density 、 Metal 、 Photochemistry 、 Electric field 、 Polarization (electrochemistry) 、 Instability 、 Tautomer 、 Chemistry
摘要: In this chapter we present an overview of what is known today about the reactivity Ca2+ with different species, both from theoretical and experimental points view. We have paid particular attention to bonding characteristics complexes electron density re-distribution undergone by neutral interacting doubly charged metal, due quite intense electric field around it, which results sometimes in, dramatic polarization effects. Another important question related stability in gas phase, clear contrast instability analogous involving other metal dications, such as Cu2+ or Pb2+, only produce singly species when bases. The last part will be devoted review combined studies several reactions Ca2+. This survey include a comparison exhibited respect shown divalent ions, well some preliminary reaction uracil. Particular also catalytic effect tautomeric process these kinds biochemical compounds.
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