Performance of metal-organic framework MIL-101 after surfactant modification in the extraction of endocrine disrupting chemicals from environmental water samples
作者： Zhenzhen Huang , Hian Kee Lee
DOI: 10.1016/J.TALANTA.2015.05.006
关键词: Pulmonary surfactant 、 Desorption 、 Chromatography 、 Derivatization 、 Extraction (chemistry) 、 Chemistry 、 Matrix (chemical analysis) 、 Detection limit 、 Adsorption 、 Aqueous solution
摘要: The research presented in this paper explored the modification and application of a metal-organic framework, MIL-101, with nonionic surfactant-Triton X-114 in dispersive solid-phase extraction for the preconcentration of four endocrine disrupting chemicals (estrone, 17α-ethynylestradiol, estriol and diethylstilbestrol) from environmental water samples. Triton X-114 molecules could be adsorbed by the hydrophobic surface of the MIL-101 crystals, and thus improved the dispersibility of MIL-101 in aqueous solution by serving as a hydrophilic …
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