作者: L S Khaikin , Lev V Vilkov
DOI: 10.1070/RC1971V040N12ABEH001989
关键词: Valence (chemistry) 、 Molecule 、 Stereochemistry 、 Mutual influence 、 Computational chemistry 、 Chemistry 、 Chemical bond
摘要: The structural data for acyclic organophosphorus compounds published up to 1971 have been systematically reviewed. geometrical parameters obtained these classified in accordance with the concepts of valence states atoms molecules and types chemical bonds. Certain general relations governing structure noted on basis this classification. a specific phosphorus–element bond may vary within limits greatly exceeding experimental error as result influence immediate environment bond. However, study problem mutual not linked directly is difficult owing lack necessary data. results determination conformations are presented. bibliography includes 231 references.