Probing hydrogen bonding in solids using solid state NMR spectroscopy

作者: Kenneth Harris , AE Aliev

DOI:

关键词: Deuterium NMRCarbon-13 NMRNuclear magnetic resonance spectroscopy of nucleic acidsJ-couplingNuclear magnetic resonance crystallographyFluorine-19 NMRCarbon-13 NMR satelliteChemistryNuclear magnetic resonance spectroscopyChemical physicsAnalytical chemistry

摘要: Solid state nuclear magnetic resonance (NMR) spectroscopy is a powerful and versatile technique for probing structural dynamic properties of solid materials, can provide detailed insights into the hydrogen bonded systems. Of particular interest in this regard are NMR experiments that investigate either atom directly involved bond (employing H-1 or H-2 techniques) atoms within, close proximity of, donor acceptor groups (employing, example, C-13,(SN)-S-15, O-17, Si-29 P-31 techniques). To large extent, versatility arises from multinuclear capability, fact there considerable complementarity information studies different nuclei provide. The aim chapter to highlight some ways which techniques, encompassing both traditional recently developed methods, be exploited towards understanding fundamental solids, focusing on organic molecular materials.

参考文章(7)
Anatole Abragam, Principles of Nuclear Magnetism ,(1993)
Haeberlen Ulrich, High resolution NMR in solids : selective averaging Academic Press. ,(1976)
Colin A. Fyfe, Solid state NMR for chemists C.F.C. Press. ,(1983)
Geoffrey Bodenhausen, Richard R. Ernst, Alexander Wokaun, Alfred G. Redfield, Principles of nuclear magnetic resonance in one and two dimensions ,(1987)