Effect of Number of Cycles in Potentiodynamic Deposition of p-type Copper Oxide and its Supercapacitor Applications

作者: CV Niveditha , MJ Jabeen Fatima , Rajita Ramanarayanan , Bhabhina Ninnora Meethal , Sindhu Swaminathan

DOI: 10.1016/J.MATPR.2018.05.142

关键词: Thin filmHorizontal scan rateSpectroscopyScanning electron microscopeSupercapacitorChemical engineeringHall effectMaterials scienceCopper oxideRaman spectroscopy

摘要: Abstract A well dispersed stable film is synthesized via potentiodynamic deposition technique under ambient conditions and neutral pH. p-type copper oxide prepared potentiodynamically a scan rate of 20 mV/s in potential sphere, which reaffirmed by virtue hall measurements. The characterization tools like Gracing Incidence X-ray diffraction, Raman spectroscopy, UV-Visble photoluminescenece Scanning Electron Microscope Hall measurement are used to study the structural, optical, morphological electrical traits thin films. Film thickness plays pivotal role supercapacitor application. amelioration for application attuned repeating number cycles such as 15, 30 45. formed displays better specific capcitance value with an excellent cyclic stability 1000 having good charge retention efficiency.

参考文章(12)
Yan Wang, Zhiqiang Shi, Yi Huang, Yanfeng Ma, Chengyang Wang, Mingming Chen, Yongsheng Chen, SUPERCAPACITOR DEVICES BASED ON GRAPHENE MATERIALS Journal of Physical Chemistry C. ,vol. 113, pp. 13103- 13103 ,(2009) , 10.1021/JP902214F
K. Reimann, K. Syassen, Raman scattering and photoluminescence inCu2O under hydrostatic pressure Physical Review B. ,vol. 39, pp. 11113- 11119 ,(1989) , 10.1103/PHYSREVB.39.11113
T Mahalingam, J.S.P Chitra, S Rajendran, M Jayachandran, Mary Juliana Chockalingam, Galvanostatic deposition and characterization of cuprous oxide thin films Journal of Crystal Growth. ,vol. 216, pp. 304- 310 ,(2000) , 10.1016/S0022-0248(00)00416-4
Chaoqun Dong, Yan Wang, Junling Xu, Guanhua Cheng, Wanfeng Yang, Tianyi Kou, Zhonghua Zhang, Yi Ding, 3D binder-free Cu2O@Cu nanoneedle arrays for high-performance asymmetric supercapacitors Journal of Materials Chemistry. ,vol. 2, pp. 18229- 18235 ,(2014) , 10.1039/C4TA04329D
Wilman Septina, Shigeru Ikeda, M. Alam Khan, Takeshi Hirai, Takashi Harada, Michio Matsumura, Laurence M. Peter, Potentiostatic electrodeposition of cuprous oxide thin films for photovoltaic applications Electrochimica Acta. ,vol. 56, pp. 4882- 4888 ,(2011) , 10.1016/J.ELECTACTA.2011.02.075
D.P. Dubal, D.S. Dhawale, R.R. Salunkhe, V.S. Jamdade, C.D. Lokhande, Fabrication of copper oxide multilayer nanosheets for supercapacitor application Journal of Alloys and Compounds. ,vol. 492, pp. 26- 30 ,(2010) , 10.1016/J.JALLCOM.2009.11.149
G Binitha, MS Soumya, Asha Anish Madhavan, P Praveen, A Balakrishnan, KRV Subramanian, MV Reddy, Shantikumar V Nair, A Sreekumaran Nair, N Sivakumar, None, Electrospun α-Fe2O3 nanostructures for supercapacitor applications Journal of Materials Chemistry. ,vol. 1, pp. 11698- 11704 ,(2013) , 10.1039/C3TA12352A
Rudra Kumar, Prabhakar Rai, Ashutosh Sharma, Facile synthesis of Cu2O microstructures and their morphology dependent electrochemical supercapacitor properties RSC Advances. ,vol. 6, pp. 3815- 3822 ,(2016) , 10.1039/C5RA20331G
C. V. Niveditha, M. J. Jabeen Fatima, S. Sindhu, Comprehensive Interfacial Study of Potentio-Dynamically Synthesized Copper Oxide Thin Films for Photoelectrochemical Applications Journal of The Electrochemical Society. ,vol. 163, ,(2016) , 10.1149/2.0971606JES
B. Saravanakumar, Kamatchi K. Purushothaman, G. Muralidharan, Interconnected V2O5 nanoporous network for high-performance supercapacitors. ACS Applied Materials & Interfaces. ,vol. 4, pp. 4484- 4490 ,(2012) , 10.1021/AM301162P