A primer on organosilicon chemistry.

作者: Ian Fleming

DOI: 10.1002/9780470513323.CH7

关键词: ElectrophileOrganic synthesisChemistryOrganic chemistryGroup (periodic table)MetalSilylationOrganosiliconHydrogenDouble bond

摘要: Organosilicon chemistry is easily understood because a few generalizations allow us to compare it with the of carbon, hydrogen and metals. A silyl group used in organic synthesis as metallic substitute for atom, enough character control both site attack by an electrophile position final double bond. The can be thought kind super-proton. biochemistry beginning exist possibility incorporating groups into drugs, secondary metabolism silicon-containing compounds being studied.

参考文章(9)
Reinhold Tacke, Ulrich Wannagat, Syntheses and properties of bioactive organo-silicon compounds. Topics in Current Chemistry. ,vol. 84, pp. 1- 75 ,(1979) , 10.1007/BFB0048522
Ralph J. Fessenden, Joan S. Fessenden, Trends in Organosilicon Biological Research Advances in Organometallic Chemistry. ,vol. 18, pp. 275- 299 ,(1980) , 10.1016/S0065-3055(08)60310-X
M. G. Voronkov, Biological activity of silatranes. Topics in Current Chemistry. ,vol. 84, pp. 77- 135 ,(1979) , 10.1007/978-1-4613-4018-8_19
Peter Brownbridge, Silyl Enol Ethers in Synthesis - Part II Synthesis. ,vol. 1983, pp. 85- 104 ,(1983) , 10.1055/S-1983-30234
Meinrat O. Andreae, Philip N. Froelich, Arsenic, antimony, and germanium biogeochemistry in the Baltic Sea Tellus B. ,vol. 36, pp. 101- 117 ,(1984) , 10.3402/TELLUSB.V36I2.14880
Peter D. Moore, Plant ecology: Photosynthetic pathways in aquatic plants Nature. ,vol. 304, pp. 310- 310 ,(1983) , 10.1038/304310A0
Ian Fleming, Andrew Pearce, Controlling the outcome of a carbocation-initiated cyclisation Journal of the Chemical Society, Perkin Transactions 1. ,vol. 12, pp. 251- 1819 ,(1981) , 10.1039/P19810000251
William P. Weber, Silicon Reagents for Organic Synthesis Reactivity and Structure Concepts in Organic Chemistry. ,(1983) , 10.1007/978-3-642-68661-0