作者: M. Zubitur , M.A. Gómez , M. Cortázar
DOI: 10.1016/J.POLYMDEGRADSTAB.2009.01.026
关键词: Sulfonate 、 Chemical engineering 、 Layered double hydroxides 、 Fourier transform infrared spectroscopy 、 Thermogravimetric analysis 、 Nanocomposite 、 Polymer chemistry 、 Thermal stability 、 Materials science 、 Thermal decomposition 、 Dodecylbenzene
摘要: Nanocomposites based on layered double hydroxides (LDH) and poly(p-dioxanone) (PPDO) were prepared by melt processing using dodecylbenzene sulfonate (DBS) 4-hydroxybenzene (HBS) as organic modifiers. The incorporation of anions in LDH was demonstrated wide-angle X-ray scattering (WAXS) Fourier transform infrared (FTIR). dispersion degree the organically modified LDHs PPDO matrix analyzed WAXS, indicating that only with HBS exfoliated. effect thermal stability studied thermogravimetric analysis (TGA). enhanced due to shielding exfoliated layers. In contrast, DBS produced a decrease PPDO, probably hydrolytic decomposition ester group. also showed organo-modified did not modify mechanism polymer, but had an stability.