Environmental monitoring of heavy metals and arsenic from Ag-Pb-Zn mining: a case study over two millennia.
作者： Doris Stüben , Zsolt Berner , Birgitta Kappes , Harald Puchelt
关键词: Environmental science 、 Waste disposal 、 Soil contamination 、 Environmental engineering 、 Tailings 、 Water pollution 、 Municipal solid waste 、 Leaching (metallurgy) 、 Environmental monitoring 、 Carbonate
摘要: 2000 years of mining activity at Wiesloch, Germany left behind a legacy wastes, some which have extremely high contents toxic elements like As, Cd, Tl, Sb, Pb and Zn. To evaluate their long-term impact on different environmental compartments, the detailed monitoring presented here focused mineralogical chemical characterization waste materials, consisting dumpings with ore fragments, flotation tailings medieval metallurgical slags. Leaching experiments these using eluents compositions pHs were carried out to assess conditions governing mobilization re-fixation species. It was shown, that carbonate host rock mineralization, loess blanket covering area organically rich municipal sewage sludges deposited top tailings, represent potential barriers dispersion over much larger area. Moreover, particulate emissions from steep, unvegetated escarpments tailing heaps continuous thread environment.
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sci-hub.se 参考文章(18)
Domy C. Adriano, Trace Elements in the Terrestrial Environment ,(1986)
Konrad Bates Krauskopf, Dennis K. Bird, Introduction to geochemistry ,(1967)
Diederik Jan Postma, C.A.J. Appelo, Geochemistry, groundwater and pollution ,(1993)
S. G. Benner, D. W. Blowes, W. D. Gould, R. B. Herbert,, C. J. Ptacek, Geochemistry of a Permeable Reactive Barrier for Metals and Acid Mine Drainage Environmental Science & Technology. ,vol. 33, pp. 2793- 2799 ,(1999) , 10.1021/ES981040U
Bruce E. Taylor, Mark C. Wheeler, Darrel Kirk Nordstrom, Isotope composition of sulphate in acid mine drainage as measure of bacterial oxidation Nature. ,vol. 308, pp. 538- 541 ,(1984) , 10.1038/308538A0
K. SARVESWARA RAO, R. P. DAS, H. S. RAY, Study of leaching of multimetal sulphides through an interdisciplinary approach Mineral Processing and Extractive Metallurgy Review. ,vol. 7, pp. 209- 233 ,(1991) , 10.1080/08827509108952672
H.W. Nesbitt, I.J. Muir, A.R. Prarr, Oxidation of arsenopyrite by air and air-saturated, distilled water, and implications for mechanism of oxidation Geochimica et Cosmochimica Acta. ,vol. 59, pp. 1773- 1786 ,(1995) , 10.1016/0016-7037(95)00081-A
D. Brion, Etude par spectroscopie de photoelectrons de la degradation superficielle de FeS2, CuFeS2, ZnS et PbS a l'air et dans l'eau Applications of Surface Science. ,vol. 5, pp. 133- 152 ,(1980) , 10.1016/0378-5963(80)90148-8
Matthew L. Pierce, Carleton B. Moore, Adsorption of arsenite and arsenate on amorphous iron hydroxide Water Research. ,vol. 16, pp. 1247- 1253 ,(1982) , 10.1016/0043-1354(82)90143-9
Mark A. Williamson, J.Donald Rimstidt, The kinetics and electrochemical rate-determining step of aqueous pyrite oxidation Geochimica et Cosmochimica Acta. ,vol. 58, pp. 5443- 5454 ,(1994) , 10.1016/0016-7037(94)90241-0