Catalytic aerobic oxidation of ethylbenzene over Co/SBA-15
作者： Hong Ma , Jie Xu , Chen Chen , Qiaohong Zhang , Jianbo Ning
DOI: 10.1007/S10562-007-9019-7
关键词: Catalysis 、 Organometallic chemistry 、 Chemistry 、 Heterogeneous catalysis 、 Ethylbenzene 、 Inorganic chemistry 、 Mesoporous material 、 Cobalt oxide
摘要: Co(II)O was highly dispersed in the mesopores of SBA-15 by alcoholic impregnation method and characterized XRD, TEM, UV-VIS DRS, TPR, XRF techniques. It found that tetrahedral coordinated stabilized at low Co-loading. Co/SBA-15 showed much higher activity than Co(OAc)(2) or Co3O4 liquid-phase aerobic oxidation ethylbenzene under solvent-free condition.
springer.com
sci-hub.se 参考文章(23)
Gopinathan Sankar, Robert Raja, John Meurig Thomas, Redox solid catalysts for the selective oxidation of cyclohexane in air Catalysis Letters. ,vol. 55, pp. 15- 23 ,(1998) , 10.1023/A:1019093703743
R. Anand, M.S. Hamdy, Ulf Hanefeld, Thomas Maschmeyer, Liquid-Phase Oxidation of Cyclohexane over Co-TUD-1 Catalysis Letters. ,vol. 95, pp. 113- 117 ,(2004) , 10.1023/B:CATL.0000027283.70453.1A
Joongjai Panpranot, Surajee Kaewkun, Piyasan Praserthdam, James G. Goodwin, Jr., Effect of Cobalt Precursors on the Dispersion of Cobalt on MCM-41 Catalysis Letters. ,vol. 91, pp. 95- 102 ,(2003) , 10.1023/B:CATL.0000006323.17873.78
Eric van Steen, Gary S. Sewell, Rafene A. Makhothe, Craig Micklethwaite, Heiko Manstein, Martijn de Lange, Cyril T. O'Connor, TPR Study on the Preparation of Impregnated Co/SiO2Catalysts Journal of Catalysis. ,vol. 162, pp. 220- 229 ,(1996) , 10.1006/JCAT.1996.0279
Hong Ma, Jie Xu, Qiaohong Zhang, Hong Miao, Wenhai Wu, Selective oxidation of ethylbenzene by a biomimetic combination: Hemin and N-hydroxyphthalimide (NHPI) Catalysis Communications. ,vol. 8, pp. 27- 30 ,(2007) , 10.1016/J.CATCOM.2006.05.023
Jamal El Haskouri, Saúl Cabrera, Carlos J. Gómez-García, Carmen Guillem, Julio Latorre, Aurelio Beltrán, Daniel Beltrán, M. Dolores Marcos, Pedro Amorós, High Cobalt Content Mesoporous Silicas Chemistry of Materials. ,vol. 16, pp. 2805- 2813 ,(2004) , 10.1021/CM049772A
Akkihebbal Krishnamurthy Suresh, Man Mohan Sharma, Tamarapu Sridhar, Engineering Aspects of Industrial Liquid-Phase Air Oxidation of Hydrocarbons Industrial & Engineering Chemistry Research. ,vol. 39, pp. 3958- 3997 ,(2000) , 10.1021/IE0002733
R.A. Sheldon, I.W.C.E. Arends, H.E.B. Lempers, Liquid phase oxidation at metal ions and complexes in constrained environments Catalysis Today. ,vol. 41, pp. 387- 407 ,(1998) , 10.1016/S0920-5861(98)00027-3
Wagner A Carvalho, Paula B Varaldo, Martin Wallau, Ulf Schuchardt, None, Mesoporous redox molecular sieves analogous to MCM-41 Zeolites. ,vol. 18, pp. 408- 416 ,(1997) , 10.1016/S0144-2449(97)00031-6
Guanyu Yang, Qiaohong Zhang, Hong Miao, Xinli Tong, Jie Xu, Selective Organocatalytic Oxygenation of Hydrocarbons by Dioxygen Using Anthraquinones and N-Hydroxyphthalimide Organic Letters. ,vol. 7, pp. 263- 266 ,(2005) , 10.1021/OL047749P