Allenyl to alkenylcarbyne tautomerization at the Ru-Si bond of Ru(κP, P, Si) pincer complexes

作者： María J Bernal , Marta Martín , Eduardo Sola , None

DOI: 10.1021/OM501238D

关键词: Chemistry 、 Tautomer 、 Dimer 、 Medicinal chemistry 、 Pincer movement 、 Reagent

摘要: The reactions of the dimer [Ru(μ-Cl){κP,P,Si-Si(Me)(C6H4-2-PiPr2)2}]2 (1) with 2-methyl-3-butyn-2-ol and 3-chloro-3-methyl-1-butyne are reported. former stops at reagent coordination step f...

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