The effect of the structure and structural changes of the stationary phase on the retention characteristics of solutes. I. The study of interactions in solutions
作者： V. Pacáková , H. Ullmannová
DOI: 10.1007/BF02268855
关键词: Thermodynamics 、 Analytical chemistry 、 Chemistry 、 Stationary phase
摘要: Interactions between n-octadecane and its monofunctional derivatives (1-chloro-, 1-hydroxy-), used as stationary phases, solutes of various structural types have been studied. Using open tubular columns, ensuring a high separation efficiency relative inertness the inner surface, retention data were measured from them specific volumes, indexes, differential solution heats calculated. Correlations quantities structures both phases are discussed.
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