Silver(I) 2,2'-(1,2-Phenylenedisulfanediyl)diacetic Acid as a Molecular Building Block for a Silver(I)-Cadmium(II) Coordination Polymer.
作者： Ioana Grosu , Christiane Berghof , Peter Lönnecke , Luminita Silaghi-Dumitrescu , Evamarie Hey-Hawkins
DOI: 10.3390/MOLECULES20058020
关键词: Polymer chemistry 、 Ligand 、 Cadmium 、 Structure analysis 、 Block (periodic table) 、 Coordination polymer 、 Stereochemistry 、 Chemistry 、 Denticity
摘要: Starting from heterotopic multidentate ligand 2,2'-(1,2-phenylenedisulfanediyl)diacetic acid, (RS,RS,RS,RS/SS,SS,SS,SS)-[Ag{1,2-C6H4(SCH2COOH)2-κ2S,S'}2]BF4 (1) was prepared and further used as a building block for the synthesis of heterobimetallic Ag-Cd coordination polymer [Ag2Cd2{1,2-(OOCCH2S)2C6H4}3 (H2O)3·5H2O]n (2). Both complexes were characterized by X-ray structure analysis conventional spectroscopic techniques.
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