Boltzmann statistics and radiationless decay in large molecules: Optical selection studies
作者： William M. Gelbart , Kenneth G. Spears , Karl F. Freed , Joshua Jortner , Stuart A. Rice
DOI: 10.1016/0009-2614(70)85092-8
关键词: Reaction rate constant 、 Excited electronic state 、 Maxwell–Boltzmann statistics 、 Vibrational energy 、 Atomic physics 、 Molecule 、 Excited state 、 Chemistry 、 Physical and Theoretical Chemistry 、 General Physics and Astronomy
摘要: Abstract We elaborate upon the conceptual value of a recent formulation theory radiationless transitions, and determine dependence nonradiative rate constant on excess vibrational energy in excited electronic state. Measurements lifetimes benzene to individual vibronic states are reported. Our rough numerical calculations found be consistent with experimental data.
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