Pseudorotaxanes with Self‐Sorted Sequence and Stereochemical Orientation
作者： Carmen Talotta , Carmine Gaeta , Zhenhui Qi , Christoph A. Schalley , Placido Neri
关键词: Sequence (biology) 、 Calixarene 、 Rotaxane 、 Stereochemistry 、 Supramolecular chemistry 、 Chemistry 、 Orientation (graph theory) 、 Self sorting
摘要: have developed into a high-interest research area.Like their natural analogues, they form selectively definedand small number of supramolecular assemblies out ofa significantly larger pool possible assemblies. Theefficiency synthetic self-sorting system is related to itsability discriminate between structurally similar individualsubunits. A fundamental step towards mimicking the effi-ciency and complexity systems designa able sort species that simultaneouslydiffer at sequence stereochemical levels. Previously,one us reported heteropseudo[3]rotaxane
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