N-Heterocyclic Carbene Catalyzed Photoenolization/Diels-Alder Reaction of Acid Fluorides.

作者: Andreas Mavroskoufis , Keerthana Rajes , Paul Golz , Arush Agrawal , Vincent Ruß

DOI: 10.1002/ANIE.201914456

关键词: Photochemical reactivityOrganocatalysisCatalysisMedicinal chemistryCarbeneStoichiometryDiels–Alder reactionLight activationUva irradiationChemistry

摘要: … CO 3 , the imidazolylidene IMe reacts with acid fluoride 4, releasing … react with the dienophile 2 in a cycloaddition process. This reaction could feasibly occur in a concerted Diels–Alder …

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