High-yield hydrogen production by supercritical water gasification of various feedstocks: Alcohols, glucose, glycerol and long-chain alkanes
作者： Ratna F. Susanti , Laras W. Dianningrum , Taewoo Yum , Yunje Kim , Youn-Woo Lee
DOI: 10.1016/J.CHERD.2014.01.003
关键词: Diesel fuel 、 Gasoline 、 Methanol 、 Hydrogen production 、 Biodiesel 、 Supercritical fluid 、 Hydrocarbon 、 Chemistry 、 Organic chemistry 、 Raw material
摘要: Abstract Continuous supercritical water gasification (SCWG) of various feedstocks C1–C16 was conducted to produce hydrogen-rich gas. These represent model compounds biomass such as methanol/ethanol (alcohol-type), glucose and glycerol (byproducts biodiesel synthesis), petroleum fuels iso-octane/n-octane (gasoline), n-decane/n-dodecane (jet fuels) n-hexadecane (diesel). Almost complete all the achieved at 25 MPa, 740 °C 10 wt% with low total organic carbon values their liquid effluents. The hydrogen gas yields each feedstock were very similar theoretical equilibrium estimated by Gibbs free energy minimization. SCWG different temperatures (650 740 °C) concentrations (10 20 wt%) revealed that methanol ethanol (alcohols), simple oxygenated hydrocarbons, easier be gasified, producing negligible amounts products, when compared long-chain hydrocarbons (iso-octane n-decane) under identical conditions. When concentration increased from 10 20 wt%, ratio iso-octane decreased 1.02 0.79 while n-decane 1.12 1.50, implying a branched hydrocarbon may more resistant in water.
core.ac.uk 
sci-hub.se 参考文章(67)
Zhong Yi Ding, Michael A. Frisch, Lixiong Li, Earnest F. Gloyna, Catalytic Oxidation in Supercritical Water Industrial & Engineering Chemistry Research. ,vol. 35, pp. 3257- 3279 ,(1996) , 10.1021/IE960022N
Jianli Yu, Phillip E. Savage, Decomposition of Formic Acid under Hydrothermal Conditions Industrial & Engineering Chemistry Research. ,vol. 37, pp. 2- 10 ,(1998) , 10.1021/IE970182E
Ben F.M. Kuster, Herman M.G. Temmink, The influence of pH and weak-acid anions on the dehydration of d-fructose Carbohydrate Research. ,vol. 54, pp. 185- 191 ,(1977) , 10.1016/S0008-6215(00)84808-9
XH Hao, LJ Guo, Xiao'an Mao, XM Zhang, XJ Chen, None, Hydrogen production from glucose used as a model compound of biomass gasified in supercritical water International Journal of Hydrogen Energy. ,vol. 28, pp. 55- 64 ,(2003) , 10.1016/S0360-3199(02)00056-3
A BYRD, K PANT, R GUPTA, Hydrogen production from glycerol by reforming in supercritical water over Ru/Al2O3 catalyst Fuel. ,vol. 87, pp. 2956- 2960 ,(2008) , 10.1016/J.FUEL.2008.04.024
Yongchun Zhang, Jun Zhang, Liang Zhao, Changdong Sheng, Decomposition of Formic Acid in Supercritical Water Energy & Fuels. ,vol. 24, pp. 95- 99 ,(2010) , 10.1021/EF9005093
Bernard M. Kabyemela, Tadafumi Adschiri, Roberto M. Malaluan, Kunio Arai, Glucose and fructose decomposition in subcritical and supercritical water: Detailed reaction pathway, mechanisms, and kinetics Industrial & Engineering Chemistry Research. ,vol. 38, pp. 2888- 2895 ,(1999) , 10.1021/IE9806390
In-Gu Lee, Mi-Sun Kim, Son-Ki Ihm, Gasification of Glucose in Supercritical Water Industrial & Engineering Chemistry Research. ,vol. 41, pp. 1182- 1188 ,(2002) , 10.1021/IE010066I
Meng Ni, Dennis Y.C. Leung, Michael K.H. Leung, A review on reforming bio-ethanol for hydrogen production International Journal of Hydrogen Energy. ,vol. 32, pp. 3238- 3247 ,(2007) , 10.1016/J.IJHYDENE.2007.04.038
Supaporn Therdthianwong, Nawadee Srisiriwat, Apichai Therdthianwong, Eric Croiset, Hydrogen production from bioethanol reforming in supercritical water Journal of Supercritical Fluids. ,vol. 57, pp. 58- 65 ,(2011) , 10.1016/J.SUPFLU.2011.02.005