Covalent Assembled Osmium-Chromophore-Based Monolayers: Chemically Induced Modulation of Optical Properties in the Visible Region
作者： Tarkeshwar Gupta , Marc Altman , Atindra D. Shukla , Dalia Freeman , Gregory Leitus
DOI: 10.1021/CM0523539
关键词: Modulation 、 Metal 、 Chromophore 、 Photochemistry 、 Redox 、 Oxidation state 、 Osmium 、 Covalent bond 、 Monolayer 、 Chemistry
摘要: Chemical addressing of the metal oxidation state an osmium-based chromophore monolayer results in modulation optical properties entire visible region (400−750 nm). The monolayers are thermally robust, and 25 Os2+/Os3+ redox cycles demonstrated.
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