Electron beam atmospheric pressure cold plasma decomposition of carbon tetrachloride and trichloroethylene.

作者: Mathias. Koch , Daniel R. Cohn , Richard M. Patrick , Matthew P. Schuetze , Leslie. Bromberg

DOI: 10.1021/ES00012A009

关键词: Chemical decompositionChain reactionPlasmaChlorineInorganic chemistryElectronAtmospheric pressureDecompositionReaction mechanismChemistry

摘要: The cold plasma decomposition of carbon tetrachloride (CCl 4 ) and trichloroethylene (C 2 HCl 3 at dilute concentrations in dry wet air atmospheric pressure was investigated. generated a tunable reactor, where the electron concentration is controlled by an beam average energy superimposed sub-breakdown electric field. expense for decomposition, i.e., per molecule decomposed, as well intermediate final products were determined. Moreover, likely reaction mechanisms CCl C are presented. These based on bimolecular dissociative attachment both -HCl additionally chlorine chain . present work provides reference development advanced oxidation process basis reactor. Such would be especially suitable treatment contaminated with chemical compounds that dissociatively attach electrons.

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