作者: Mathias. Koch , Daniel R. Cohn , Richard M. Patrick , Matthew P. Schuetze , Leslie. Bromberg
DOI: 10.1021/ES00012A009
关键词: Chemical decomposition 、 Chain reaction 、 Plasma 、 Chlorine 、 Inorganic chemistry 、 Electron 、 Atmospheric pressure 、 Decomposition 、 Reaction mechanism 、 Chemistry
摘要: The cold plasma decomposition of carbon tetrachloride (CCl 4 ) and trichloroethylene (C 2 HCl 3 at dilute concentrations in dry wet air atmospheric pressure was investigated. generated a tunable reactor, where the electron concentration is controlled by an beam average energy superimposed sub-breakdown electric field. expense for decomposition, i.e., per molecule decomposed, as well intermediate final products were determined. Moreover, likely reaction mechanisms CCl C are presented. These based on bimolecular dissociative attachment both -HCl additionally chlorine chain . present work provides reference development advanced oxidation process basis reactor. Such would be especially suitable treatment contaminated with chemical compounds that dissociatively attach electrons.