Column studies to investigate the fate of veterinary antibiotics in clay soils following slurry application to agricultural land.

作者: Paul Kay , Paul A. Blackwell , Alistair B.A. Boxall

DOI: 10.1016/J.CHEMOSPHERE.2005.01.028

关键词: Veterinary medicineSlurryEnvironmental scienceLeaching modelSoil contaminationLeaching (agriculture)AmendmentLoamTillageSoil water

摘要: The environment may be exposed to veterinary medicines administered livestock due the application of organic fertilisers land. For other groups substances that are applied agricultural land (e.g. pesticides), preferential flow in underdrained clay soils has been identified as an extremely important pathway by which pollution surface waters can occur. Three soil column leaching experiments have therefore carried out using a investigate fate range antibiotics from sulphonamide, tetracycline and macrolide groups. These studies complemented at field semi-field scales, well modelling being reported separate papers. Each study had different objective. first examined effect pig slurry on mobility loam soil. second experiment investigated changes water pH slurry. final quantified extent tillage prior reduce antibiotic residues found It was no impact oxytetracycline although affected significantly application. also shown pre-tillage substantially through macroporous soils.

参考文章(45)
Bent Halling-Sørensen, Anne Lykkeberg, Flemming Ingerslev, Paul Blackwell, Jette Tjørnelund, Characterisation of the abiotic degradation pathways of oxytetracyclines in soil interstitial water using LC–MS–MS Chemosphere. ,vol. 50, pp. 1331- 1342 ,(2003) , 10.1016/S0045-6535(02)00766-X
Flemming Ingerslev, Lars Toräng, Marie-Louise Loke, Bent Halling-Sørensen, Niels Nyholm, Primary biodegradation of veterinary antibiotics in aerobic and anaerobic surface water simulation systems Chemosphere. ,vol. 44, pp. 865- 872 ,(2001) , 10.1016/S0045-6535(00)00479-3
Alistair B.A. Boxall, Paul Blackwell, Romina Cavallo, Paul Kay, Johannes Tolls, The sorption and transport of a sulphonamide antibiotic in soil systems. Toxicology Letters. ,vol. 131, pp. 19- 28 ,(2002) , 10.1016/S0378-4274(02)00063-2
E. J. Kladivko, G. E. Van Scoyoc, E. J. Monke, K. M. Oates, W. Pask, Pesticide and Nutrient Movement into Subsurface Tile Drains on a Silt Loam Soil in Indiana Journal of Environmental Quality. ,vol. 20, pp. 264- 270 ,(1991) , 10.2134/JEQ1991.00472425002000010043X
Ali M Sadeghi, Allan R Isensee, Adel Shirmohammadi, Influence of soil texture and tillage on herbicide transport Chemosphere. ,vol. 41, pp. 1327- 1332 ,(2000) , 10.1016/S0045-6535(00)00028-X
Johannes Tolls, Sorption of veterinary pharmaceuticals in soils: a review. Environmental Science & Technology. ,vol. 35, pp. 3397- 3406 ,(2001) , 10.1021/ES0003021
Andrew C Johnson, Atul H Haria, Chaman L Bhardwaj, Richard J Williams, Allan Walker, Preferential Flow Pathways and Their Capacity to Transport Isoproturon in a Structured Clay Soil Pesticide Science. ,vol. 48, pp. 225- 237 ,(1996) , 10.1002/(SICI)1096-9063(199611)48:3<225::AID-PS462>3.0.CO;2-D
Michel Y Haller, Stephan R Müller, Christa S McArdell, Alfredo C Alder, Marc J.-F Suter, Quantification of veterinary antibiotics (sulfonamides and trimethoprim) in animal manure by liquid chromatography–mass spectrometry Journal of Chromatography A. ,vol. 952, pp. 111- 120 ,(2002) , 10.1016/S0021-9673(02)00083-3
F. Worrall, A. Parker, J. E. Rae, A. C. Johnson, A Study of Suspended and Colloidal Matter in the Leachate from Lysimeters and its Role in Pesticide Transport Journal of Environmental Quality. ,vol. 28, pp. 595- 604 ,(1999) , 10.2134/JEQ1999.00472425002800020025X