Palladium-catalyzed carbonylative C-H activation of heteroarenes.
作者： Xiao-Feng Wu , Pazhamalai Anbarasan , Helfried Neumann , Matthias Beller
关键词: Organic chemistry 、 Medicinal chemistry 、 Benzene 、 Molecule 、 Palladium 、 Catalysis 、 Aryl 、 Ligand 、 Ketone 、 Chemistry 、 Carbonylation
摘要: Heteroaryl aryl ketones and di(heteroaryl) are obtained from iodides various heteroarenes under optimized conditions concerning the ratios of partners reagents, CO pressure ligand.
sci-hub.se 参考文章(73)
Vincent Ritleng, Claude Sirlin, Michel Pfeffer, Ru-, Rh-, and Pd-Catalyzed C-C Bond Formation Involving C-H Activation and Addition on Unsaturated Substrates: Reactions and Mechanistic Aspects Chemical Reviews. ,vol. 102, pp. 1731- 1770 ,(2002) , 10.1021/CR0104330
Kiyoshi Kikukawa, Tohru Idemoto, Atsuhiko Katayama, Kiyoshi Kono, Fumio Wada, Tsutomu Matsuda, Reaction of diazonium salts with transition metals. Part 13. Palladium-catalyzed carbonylative coupling of arenediazonium salts with organotin reagents to give aromatic ketones Journal of The Chemical Society-perkin Transactions 1. pp. 1511- 1514 ,(1987) , 10.1039/P19870001511
Helfried Neumann, Anne Brennführer, Matthias Beller, A general synthesis of diarylketones by means of a three-component cross-coupling of aryl and heteroaryl bromides, carbon monoxide, and boronic acids. Chemistry: A European Journal. ,vol. 14, pp. 3645- 3652 ,(2008) , 10.1002/CHEM.200800001
Jianming Liu, Xingao Peng, Wei Sun, Yongwei Zhao, Chungu Xia, Magnetically Separable Pd Catalyst for Carbonylative Sonogashira Coupling Reactions for the Synthesis of α,β-Alkynyl Ketones Organic Letters. ,vol. 10, pp. 3933- 3936 ,(2008) , 10.1021/OL801478Y
Tsuyoshi Kawano, Koji Hirano, Tetsuya Satoh, Masahiro Miura, A New Entry of Amination Reagents for Heteroaromatic C−H Bonds: Copper-Catalyzed Direct Amination of Azoles with Chloroamines at Room Temperature Journal of the American Chemical Society. ,vol. 132, pp. 6900- 6901 ,(2010) , 10.1021/JA101939R
Lutz Ackermann, Sebastian Barfüsser, Jola Pospech, Palladium-catalyzed direct arylations, alkenylations, and benzylations through C-H bond cleavages with sulfamates or phosphates as electrophiles. Organic Letters. ,vol. 12, pp. 724- 726 ,(2010) , 10.1021/OL9028034
Rafael S. Sánchez, Fedor A. Zhuravlev, Mechanistic evidence for a ring-opening pathway in the Pd-catalyzed direct arylation of benzoxazoles. Journal of the American Chemical Society. ,vol. 129, pp. 5824- 5825 ,(2007) , 10.1021/JA0679580
Bengü Sezen, Dalibor Sames, Cobalt-catalyzed arylation of azole heteroarenes via direct C-H bond functionalization. Organic Letters. ,vol. 5, pp. 3607- 3610 ,(2003) , 10.1021/OL035313O
Masato Tanaka, Unsymmetrical ketone synthesis from organic halides, carbon monoxide, and organotin compounds catalyzed by a palladium complex Tetrahedron Letters. ,vol. 20, pp. 2601- 2602 ,(1979) , 10.1016/S0040-4039(01)86360-7
Shangdong Yang, Bijie Li, Xiaobing Wan, Zhangjie Shi, Ortho Arylation of Acetanilides via Pd(II)-Catalyzed C−H Functionalization Journal of the American Chemical Society. ,vol. 129, pp. 6066- 6067 ,(2007) , 10.1021/JA070767S