Selective nitration of styrenes with clayfen and clayan: A solvent-free synthesis of β-nitrostyrenes

作者: Rajender S. Varma , Kannan P. Naicker , Per J. Liesen

DOI: 10.1016/S0040-4039(98)00740-0

关键词: Solvent freeStyreneNitrationChemistryReagentOrganic chemistry

摘要: Abstract A facile solvent-free synthesis of β-nitrostyrenes is described from styrene and its substituted derivatives using inexpensive ‘doped’ clay reagents, clayfen clayan.

参考文章(42)
J. M. Masnovi, J. K. Kochi, II. Thermal nitration of olefins with tetranitromethane. Evidence for homolytic initiation of a chain mechanism Recueil des Travaux Chimiques des Pays-Bas. ,vol. 105, pp. 286- 295 ,(2010) , 10.1002/RECL.19861050910
Rajender S. Varma, Jagannath B. Lamture, Manju Varma, Alumina-mediated cleavage of t-butyldimethylsilyl ethers Tetrahedron Letters. ,vol. 34, pp. 3029- 3032 ,(1993) , 10.1016/S0040-4039(00)93370-7
P. Pennetreau, P. Laszlo, A. Cornelis, Nitration of estrone into 2-nitroestrone by clay-supported ferric nitrate Journal of Organic Chemistry. ,vol. 48, pp. 4771- 4772 ,(1983)
E. J. Corey, Herbert Estreicher, A new synthesis of conjugated nitro cyclo olefins, unusually versatile synthetic intermediates Journal of the American Chemical Society. ,vol. 100, pp. 6294- 6295 ,(1978) , 10.1021/JA00487A088
Rajender S. Varma, Rajender Dahiya, Rajesh K. Saini, Iodobenzene diacetate on alumina: Rapid oxidation of alcohols to carbonyl compounds in solventless system using microwaves☆ Tetrahedron Letters. ,vol. 38, pp. 7029- 7032 ,(1997) , 10.1016/S0040-4039(97)01660-2
Takashi Hayama, Shuji Tomoda, Yoshito Takeuchi, Yujiro Nomura, Synthesis of conjugated nitroalkenes via nitroselenenylation of alkenes Tetrahedron Letters. ,vol. 23, pp. 4733- 4734 ,(1982) , 10.1016/S0040-4039(00)85699-3
Rajender S. Varma, Rajender Dahiya, Rajesh K. Saini, Solid state regeneration of ketones from oximes on wet silica supported sodium periodate using microwaves Tetrahedron Letters. ,vol. 38, pp. 8819- 8820 ,(1997) , 10.1016/S0040-4039(97)10521-4
Wing-Wah Sy, Arnold W. By, Nitration of substituted styrenes with nitryl iodide Tetrahedron Letters. ,vol. 26, pp. 1193- 1196 ,(1985) , 10.1016/S0040-4039(00)98431-4
Rajender S. Varma, Rajesh K. Saini, Wet alumina supported chromium(VI) oxide: Selective oxidation of alcohols in solventless system Tetrahedron Letters. ,vol. 39, pp. 1481- 1482 ,(1998) , 10.1016/S0040-4039(98)00010-0