Transition Metal Corrole Coordination Chemistry
作者： Joshua H. Palmer
DOI: 10.1007/430_2011_52
关键词: Chemistry 、 Electronic structure 、 Porphyrin 、 Cobalt 、 Electron configuration 、 Reactivity (chemistry) 、 Coordination complex 、 Transition metal 、 Corrole 、 Computational chemistry 、 Photochemistry
摘要: The transition metal complexes of the non-innocent, electron-rich corrole macrocycle are discussed. A detailed summary investigations to determine physical oxidation states formally iron(IV) and cobalt(IV) corroles as well as copper(III) corroles is presented. Electronic structures and reactivity other metallocorroles also discussed, comparisons between corrole porphyrin made where data available. growing assortment second-row corrole discussed compared to first-row analogs, work describing synthesis characterization third-row corroles summarized. Emphasis placed on role spectroscopic and computational studies in elucidating electronic configuration.
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Harry B. Gray, Carl Johan Ballhausen, Molecular electronic structures: An introduction ,(1980)
Karl M. Kadish, Kevin M. Smith, Roger Guilard, The porphyrin handbook Academic Press. ,(2002)
Joel Rosenthal, Daniel G. Nocera, Oxygen Activation Chemistry of Pacman and Hangman Porphyrin Architectures Based on Xanthene and Dibenzofuran Spacers John Wiley & Sons, Ltd. pp. 483- 544 ,(2008) , 10.1002/9780470144428.CH7
Edward I. Solomon, C.J. Ballhausen, Identification of the structure of the 3T1g (I) ← 3A2g band in the Ni(H2O)6 ++ complex Molecular Physics. ,vol. 29, pp. 279- 299 ,(1975) , 10.1080/00268977500100191
Martin Gouterman, Georges H. Wagnière, Lawrence C. Snyder, Spectra of porphyrins: Part II. Four orbital model Journal of Molecular Spectroscopy. ,vol. 11, pp. 108- 127 ,(1963) , 10.1016/0022-2852(63)90011-0
Bonding in transition metal complexes pp. 97- 129 ,(2001) , 10.1039/9781847550682-00097
Irena Saltsman, Atif Mahammed, Israel Goldberg, Elena Tkachenko, Mark Botoshansky, Zeev Gross, Selective substitution of corroles: nitration, hydroformylation, and chlorosulfonation. Journal of the American Chemical Society. ,vol. 124, pp. 7411- 7420 ,(2002) , 10.1021/JA025851G
Olga Zakharieva, Volker Schünemann, Michael Gerdan, Silvia Licoccia, Sheng Cai, F. Ann Walker, Alfred X. Trautwein, Is the corrolate macrocycle innocent or noninnocent? Magnetic susceptibility, Mössbauer, 1H NMR, and DFT investigations of chloro- and phenyliron corrolates. Journal of the American Chemical Society. ,vol. 124, pp. 6636- 6648 ,(2002) , 10.1021/JA012701H
Xia Liu, Atif Mahammed, Umakanta Tripathy, Zeev Gross, Ronald P. Steer, Photophysics of Soret-excited tetrapyrroles in solution. III. Porphyrin analogues: Aluminum and gallium corroles Chemical Physics Letters. ,vol. 459, pp. 113- 118 ,(2008) , 10.1016/J.CPLETT.2008.05.038
A.M. Abeysekera, R. Grigg, J. Trocha-Grimshaw, V. Viswanatha, T.J. King, Structure and reactivity of Rh(I) complexes of polypyrrole macrocycles and their N-alkylated derivatives Tetrahedron Letters. ,vol. 17, pp. 3189- 3192 ,(1976) , 10.1016/S0040-4039(00)93876-0