Adsorption of benzene and toluene from waste gas using activated carbon activated by ZnCl 2

作者: Leila Karimnezhad , Mohammad Haghighi , Esmaeil Fatehifar

DOI: 10.1007/S11783-014-0695-4

关键词: TolueneAmorphous solidChemistryAdsorptionInorganic chemistryCarbonizationBenzeneNuclear chemistryActivated carbonYield (chemistry)Fourier transform infrared spectroscopy

摘要: A series of activated carbons with high surface area were prepared from walnut shell using chemical activation ZnCl2. In this research the carbonization stage was carried out at 500°C. The performance synthesized evaluated in adsorption benzene and toluene waste gas. influence impregnation ratio on characteristics as well their capacity investigated. agent to selected range 0.5–2.0 wt/wt. characterized XRD, SEM, BET FTIR techniques. highest carbon production yield obtained 1.5 XRD analysis illustrated that peaks intensity decreased increasing showing amorphous property samples increased. SEM revealed successful pore development ratios. increased its maximum value reached 2643 m2·g−1 2/1. indicated relative amount different acidic groups a function ratio. Experimental results for showed potential employing impregnated treatment Generally, VOC adsorbed affected by physicochemical properties carbons.

参考文章(52)
Zahra Abbasi, Mohammad Haghighi, Esmaeil Fatehifar, Nader Rahemi, Comparative synthesis and physicochemical characterization of CeO2 nanopowder via redox reaction, precipitation and sol–gel methods used for total oxidation of toluene Asia-Pacific Journal of Chemical Engineering. ,vol. 7, pp. 868- 876 ,(2012) , 10.1002/APJ.652
Yuanyuan Sun, Qinyan Yue, Baoyu Gao, Lihui Huang, Xing Xu, Qian Li, Comparative study on characterization and adsorption properties of activated carbons with H3PO4 and H4P2O7 activation employing Cyperus alternifolius as precursor Chemical Engineering Journal. ,vol. 181, pp. 790- 797 ,(2012) , 10.1016/J.CEJ.2011.11.098
Jing Wang, Peng Zhang, Jin-Qing Qi, Peng-Jun Yao, Silicon-based micro-gas sensors for detecting formaldehyde Sensors and Actuators B-chemical. ,vol. 136, pp. 399- 404 ,(2009) , 10.1016/J.SNB.2008.12.056
Qian Lin, Yanbin Jiang, Jianming Geng, Yu Qian, Removal of organic impurities with activated carbons for ultra-pure hydrogen peroxide preparation Chemical Engineering Journal. ,vol. 139, pp. 264- 271 ,(2008) , 10.1016/J.CEJ.2007.07.091
M.K.B. Gratuito, T. Panyathanmaporn, R.-A. Chumnanklang, N. Sirinuntawittaya, A. Dutta, Production of activated carbon from coconut shell : Optimization using response surface methodology Bioresource Technology. ,vol. 99, pp. 4887- 4895 ,(2008) , 10.1016/J.BIORTECH.2007.09.042
H. Treviño-Cordero, L.G. Juárez-Aguilar, D.I. Mendoza-Castillo, V. Hernández-Montoya, A. Bonilla-Petriciolet, M.A. Montes-Morán, Synthesis and adsorption properties of activated carbons from biomass of Prunus domestica and Jacaranda mimosifolia for the removal of heavy metals and dyes from water Industrial Crops and Products. ,vol. 42, pp. 315- 323 ,(2013) , 10.1016/J.INDCROP.2012.05.029
Hui Deng, Guoxue Li, Hongbing Yang, Jiping Tang, Jiangyun Tang, Preparation of activated carbons from cotton stalk by microwave assisted KOH and K2CO3 activation Chemical Engineering Journal. ,vol. 163, pp. 373- 381 ,(2010) , 10.1016/J.CEJ.2010.08.019
Ki-Joong Kim, Chan-Soon Kang, Young-Jae You, Min-Chul Chung, Myung-Wu Woo, Woon-Jo Jeong, Nam-Cook Park, Ho-Geun Ahn, Adsorption–desorption characteristics of VOCs over impregnated activated carbons Catalysis Today. ,vol. 111, pp. 223- 228 ,(2006) , 10.1016/J.CATTOD.2005.10.030