Transformation of white phosphorus in the coordination sphere of nickel complexes with σ-donating ligands
作者： Yu. H. Budnikova , A. G. Kafiyatullina , A. S. Balueva , R. M. Kuznetsov , V. I. Morozov
DOI: 10.1023/B:RUCB.0000012364.31262.CA
关键词: Nickel 、 Infrared spectroscopy 、 Crystallography 、 31p nmr spectroscopy 、 Ligand 、 Chemistry 、 White Phosphorus 、 Coordination sphere 、 Photochemistry 、 Cyclic voltammetry
摘要: Oxidation of white phosphorus in the coordination sphere nickel(ii) complex with 1,1,1-tris(diphenylphosphinomethyl)ethane and 1,1",5,5"-bis[methylenedi(p-phenylene)]di(3,7-diphenyl-1,5-diaza-3,7-diphosphacyclooctane) was shown to be possible accompanied by transformation P4 into σ-P3 ligand. The change nickel state monitored cyclic voltammetry, 31P NMR spectroscopy, ESR, IR spectroscopy.
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