Molecular iodine adsorption within Hofmann-type structures M(L)[M'(CN)4] (M = Ni, Co; M' = Ni, Pd, Pt): impact of their composition.
作者： Giovanni Massasso , María Rodríguez-Castillo , Jérôme Long , Julien Haines , Sabine Devautour-Vinot
DOI: 10.1039/C5DT02907D
关键词: Clathrate hydrate 、 Metal ions in aqueous solution 、 Octahedron 、 Pyrazine 、 Ion 、 Crystallography 、 Thermal stability 、 Metal 、 Inorganic chemistry 、 Adsorption 、 Chemistry
摘要: … Note that: (i) the use of Co II results in a slightly larger unit cell with respect to the Ni II cation, … ligand for Ni II is higher than that for Co II , and (ii) the Ni II (pz)[Pd II (CN) 4 ]·2H 2 O and Ni II …
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