Evaluation of a sequential extraction method for determining actinide fractionation in soils and sediments
作者： Michael K Schultz , William C Burnett , Kenneth G.W Inn
DOI: 10.1016/S0265-931X(97)00075-1
关键词: Organic matter 、 Reagent 、 Uranium 、 Radiochemistry 、 Actinide 、 Extraction (chemistry) 、 Fractionation 、 Nuclear chemistry 、 Fraction (chemistry) 、 Americium 、 Chemistry
摘要: Abstract A sequential chemical extraction method for the determination of geochemical fractionation Am, Pu, and U was evaluated rigorously on a single marine sediment standard ( IAEA -135). Partitioning actinides operationally defined five reagent fractions stable element analyses (Al, Ca, Fe, Mn, Ti, etc.) were performed to assist in establishing phase specificity extractions. The produces, general, results that agree within one deviation interval replicate measurements each fraction. Actinide readsorption, examined by double-spiking technique, found be significant some cases. Ethylenediamine-tetraacetic acid (EDTA) as hold-back lessen effect readsorption but seriously compromised selectivity extractants. In addition, use NaOCl destruction organic matter dissolve carbonates out sequence is not recommended carbonate-bearing materials.
elsevier.com
sci-hub.se 参考文章(32)
W C. Burnett, Kenneth G. Inn, Z C. Lin, M K. Schultz, J W. Thomas, New Directions for Natural-Matrix Standards - the NIST Speciation Workshop Radioactivity and Radiochemistry. ,vol. 7, ,(1996)
Jan Rydberg, Gregory R. Choppin, Nuclear Chemistry: Theory and Applications ,(1980)
Jan-Olov Liljenzin, Jan Rydberg, Gregory R. Choppin, Radiochemistry and nuclear chemistry ,(2002)
L. M. Shuman, Sodium Hypochlorite Methods for Extracting Microelements Associated with Soil Organic Matter Soil Science Society of America Journal. ,vol. 47, pp. 656- 660 ,(1983) , 10.2136/SSSAJ1983.03615995004700040010X
K. M. Kemner, D. B. Hunter, W. T. Elam, P. M. Bertsch, XAFS Studies of Solution-Phase Complexes of Cesium with Dibenzo-18-crown-6 Ethers The Journal of Physical Chemistry. ,vol. 100, pp. 11698- 11703 ,(1996) , 10.1021/JP9604608
Wolfgang Balzer, On the distribution of iron and manganese at the sediment/water interface: thermodynamic versus kinetic control Geochimica et Cosmochimica Acta. ,vol. 46, pp. 1153- 1161 ,(1982) , 10.1016/0016-7037(82)90001-1
T. Sterckeman, A. Gomez, H. Ciesielski, Soil and waste analysis for environmental risk assessment in France. Science of The Total Environment. ,vol. 178, pp. 63- 69 ,(1996) , 10.1016/0048-9697(95)04798-0
N. H. Aguilera, M. L. Jackson, Iron Oxide Removal from Soils and Clays1 Soil Science Society of America Journal. ,vol. 17, pp. 359- 364 ,(1953) , 10.2136/SSSAJ1953.03615995001700040015X
Francois. Rapin, Andre. Tessier, Peter G. C. Campbell, Richard. Carignan, Potential artifacts in the determination of metal partitioning in sediments by a sequential extraction procedure Environmental Science & Technology. ,vol. 20, pp. 836- 840 ,(1986) , 10.1021/ES00150A014
Edward. Tipping, Nigel B. Hetherington, John. Hilton, Dudley W. Thompson, Emma. Bowles, John. Hamilton-Taylor, Artifacts in the use of selective chemical extraction to determine distributions of metals between oxides of manganese and iron Analytical Chemistry. ,vol. 57, pp. 1944- 1946 ,(1985) , 10.1021/AC00286A035