Enantioselectivity for hydrophosphonylation of aromatic aldehydes catalyzed by lanthanum binaphthol complex. Remarkable electronic effect of aromatic substituents
作者： Tsutomu Yokomatsu , Takehiro Yamagishi , Shiroshi Shibuya
DOI: 10.1016/S0957-4166(00)80416-4
关键词: Lanthanum 、 Benzaldehyde 、 Electronic effect 、 Chemistry 、 Yield (chemistry) 、 Organic chemistry 、 Catalysis 、 Enantioselective synthesis 、 Aldehyde
摘要: Abstract Hydrophosphonylation of aromatic aldehydes with diethyl phosphite in the presence catalytic amount La-BINOL complex ( 2 ) proceeded enantioselectively to give corresponding α-hydroxyphosphonates good yield. Enantioselectivity was found depend on electronic nature para -substituents.
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