Nickelocene chemistry : I. Reactions of methylenetriphenylphosphorane with η5-cyclopentadienylnickel complexes
作者： Brian L. Booth , Kenneth G. Smith
DOI: 10.1016/S0022-328X(00)94225-6
关键词: Nickelocene 、 Medicinal chemistry 、 Ylide 、 Methylenetriphenylphosphorane 、 Photochemistry 、 Chemistry 、 Cyclopentadienyl complex 、 Cationic polymerization
摘要: Abstract Nickelocene reacts with methylenetriphenylphosphorane displacement of one the cyclopentadienyl rings to give cation [Ni(CH 2 PPh 3 ) (η 5 -C H )] + , which can also be obtained by reaction cationic complexes [Ni(η )L ]X (L or P-n-Bu Ph PCH . With [NiBr(η )(PPh ylide displaces Br - form )(η Br.
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