Synthesis and Isolation of Crystalline Alkali Metal Arene Radical Anions
作者： Skye Fortier , Efrain Maximiliano Castillo
DOI:
关键词: Solvent 、 Organic chemistry 、 Crown ether 、 Chemistry 、 Alkali metal
摘要: Certain embodiments are directed to a composition comprising complex of the general formula [M(crown ether)(solvent)n][arene−•], wherein M is an alkali metal and method making same.
lens.org 参考文章(13)
H. Bock, K. Gharagozloo-Hubmann, M. Sievert, T. Prisner, Z. Havlas, Single crystals of an ionic anthracene aggregate with a triplet ground state Nature. ,vol. 404, pp. 267- 269 ,(2000) , 10.1038/35005048
N. L. Holy, Reactions of the radical anions and dianions of aromatic hydrocarbons Chemical Reviews. ,vol. 74, pp. 243- 277 ,(1974) , 10.1021/CR60288A005
A. V. Zabula, A. S. Filatov, S. N. Spisak, A. Y. Rogachev, M. A. Petrukhina, A main group metal sandwich: five lithium cations jammed between two corannulene tetraanion decks. Science. ,vol. 333, pp. 1008- 1011 ,(2011) , 10.1126/SCIENCE.1208686
A. Rainis, M. Szwarc, Disproportionation of the lithium, sodium, and potassium salts of anthracenide and perylenide radical anions in DME and THF Journal of the American Chemical Society. ,vol. 96, pp. 3008- 3010 ,(1974) , 10.1021/JA00816A065
N. D. Scott, J. F. Walker, V. L. Hansley, Sodium Naphthalene. I. A New Method for the Preparation of Addition Compounds of Alkali Metals and Polycyclic Aromatic Hydrocarbons Journal of the American Chemical Society. ,vol. 58, pp. 2442- 2444 ,(1936) , 10.1021/JA01303A022
P. Balk, G. J. Hoijtink, J. W. H. Schreurs, Electronic spectra of mono- and di-negative aromatic ions Recueil des Travaux Chimiques des Pays-Bas. ,vol. 76, pp. 813- 823 ,(2010) , 10.1002/RECL.19570761009
Cristóbal Melero, Albert Guijarro, Miguel Yus, Structural characterization and bonding properties of lithium naphthalene radical anion, [Li+(TMEDA)2][C10H8˙−], and lithium naphthalene dianion [(Li+TMEDA)2C10H8−2] Dalton Transactions. pp. 1286- 1289 ,(2009) , 10.1039/B821119C
Thomas A. Scott, Betty A. Ooro, David J. Collins, Michael Shatruk, Andrey Yakovenko, Kim R. Dunbar, Hong-Cai Zhou, After 118 years, the isolation of two common radical anion reductants as simple, stable solids Chemical Communications. pp. 65- 67 ,(2009) , 10.1039/B815272A
Peter B. Hitchcock, Michael F. Lappert, Andrey V. Protchenko, The first crystalline alkali metal salt of a benzenoid radical anion without a stabilizing substituent and of a related dimer: X-ray structures of the toluene radical anion and of the benzene radical anion dimer potassium-crown ether salts. Journal of the American Chemical Society. ,vol. 123, pp. 189- 190 ,(2001) , 10.1021/JA005580E
A. Soncini, P.W. Fowler, Ring-current aromaticity in open-shell systems Chemical Physics Letters. ,vol. 450, pp. 431- 436 ,(2008) , 10.1016/J.CPLETT.2007.11.053