Oxygen self-diffusion and surface exchange studies of oxide electrolytes having the fluorite structure
作者： P Manning
DOI: 10.1016/S0167-2738(96)00514-0
关键词: Chemistry 、 Inorganic chemistry 、 Yttria-stabilized zirconia 、 Electrolyte 、 Oxygen 、 Secondary ion mass spectrometry 、 Activation energy 、 Fast ion conductor 、 Oxygen transport 、 Oxide
摘要: Abstract Isotopic Exchange Depth Profiling (IEDP) using Secondary Ion Mass Spectrometry (SIMS) has been used to investigate oxygen self-diffusion and surface exchange reactions in the related fluorites, yttria stabilised zirconia (YSZ) gadolinia doped ceria (CGO). The nature of reaction between gas solid explored phase analysis technique. Both YSZ CGO samples showed a change activation energy process at approximately 700 °C. In both temperature regimes two materials show similar enthalpies for reaction. At temperatures below °C is that bulk diffusion within same sample (i.e. 1 eV 0.9 CGO). greater than marked increase was observed, whilst no discernible seen transport. observed be 2.3 °C, increased 3.3 eV.
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sci-hub.se 参考文章(10)
Mixed Conducting Ceramics, T. A. Ramanarayanan, H. L. Tuller, Proceedings of the Second International Symposium on Ionic and Mixed Conducting Ceramics the Electrochemical Society. ,(1991)
John Crank, The mathematics of diffusion ,(1956)
Ken Ando, Y. Oishi, Y. Hidaka, Self‐diffusion of oxygen in single crystal thorium oxide Journal of Chemical Physics. ,vol. 65, pp. 2751- 2755 ,(1976) , 10.1063/1.433419
L. A. SIMPSON, R. E. CARTER, Oxygen Exchange and Diffusion in Calcia‐Stabilized Zirconia Journal of the American Ceramic Society. ,vol. 49, pp. 139- 144 ,(1966) , 10.1111/J.1151-2916.1966.TB15391.X
Sukhvinder P. S. Badwal, Comment on „Low‐Temperature Ionic Conductivity of 9.4‐mol%‐Yttria‐Stabilized Zironia Single Crystals” Journal of the American Ceramic Society. ,vol. 73, pp. 3718- 3719 ,(1990) , 10.1111/J.1151-2916.1990.TB04286.X
B.A. Boukamp, B.A. van Hassel, I.C. Vinke, K.J. De Vries, A.J. Burggraaf, The oxygen transfer process on solid oxide/noble metal electrodes, studied with impedance spectroscopy, dc polarization and isotope exchange Electrochimica Acta. ,vol. 38, pp. 1817- 1825 ,(1993) , 10.1016/0013-4686(93)80303-H
J KILNER, B STEELE, L ILKOV, Oxygen self-diffusion studies using negative-ion secondary ion mass spectrometry (SIMS) Solid State Ionics. ,vol. 12, pp. 89- 97 ,(1984) , 10.1016/0167-2738(84)90134-6
E Kurumchin, An isotope exchange study of the behaviour of electrochemical systems Solid State Ionics. ,vol. 42, pp. 129- 133 ,(1990) , 10.1016/0167-2738(90)90001-8
Anthony E. Hughes, Segregation in Single-Crystal Fully Stabilized Yttria-Zirconia Journal of the American Ceramic Society. ,vol. 78, pp. 369- 378 ,(1995) , 10.1111/J.1151-2916.1995.TB08810.X
Byung-Kook Kim, Soon-Ja Park, Hiro-o Hamaguchi, Determination of the Oxygen Self‐Diffusion Coefficients in Y2O3‐Containing Tetragonal Zirconia Polycrystals by Raman Spectrometric Monitoring of the 16O‐18O Exchange Reaction Journal of the American Ceramic Society. ,vol. 76, pp. 2119- 2122 ,(1993) , 10.1111/J.1151-2916.1993.TB08345.X