STRUCTURAL STUDIES OF KDP AND THE KDP-TYPE TRANSITION BY NEUTRON AND X-RAY DIFFRACTION: 1970-1985

作者: R. J. Nelmes

DOI: 10.1080/00150198708224832

关键词: Materials scienceX-ray crystallographyCondensed matter physicsWork (thermodynamics)Soft modesNeutronExperimental workNeutron diffraction

摘要: Abstract Structural work on KH2PO4, KD2PO4, RbH2PO4 and partially-deuterated CsH2AsO4 over the period 1970 to 1985, is fully reviewed. The content predominantly Edinburgh-based programme of neutron-diffraction studies, but other X-ray these isomorphs also included. Following a general presentation 1980, most recent results, conclusions current are discussed in terms four main topics: hydrogen bond, onset structural order below Tc , pressure effects, soft mode. Finally, some suggestions made for further studies closely-related theoretical experimental work.

参考文章(57)
G. L. Paul, W. Cochran, W. J. L. Buyers, R. A. Cowley, Ferroelectric Transition in KD2PO4 Physical Review B. ,vol. 2, pp. 4603- 4612 ,(1970) , 10.1103/PHYSREVB.2.4603
R. Bllnc, B. ŽekŠ, R. J. Nelmes, Proton tunnelling in KH2PO4 Phase Transitions. ,vol. 3, pp. 293- 308 ,(1983) , 10.1080/01411598308244076
Aubrey L McClellan, George C. Pimentel, Roger Hayward, The hydrogen bond ,(1960)
H J Bleif, R A Cowley, R J Nelmes, The ferroelectric fluctuation in KD2PO4 Journal of Physics C: Solid State Physics. ,vol. 15, ,(1982) , 10.1088/0022-3719/15/8/001
J. Skalyo, B. C. Frazer, G. Shirane, Ferroelectric-Mode Motion in KD 2 PO 4 Physical Review B. ,vol. 1, pp. 278- 286 ,(1970) , 10.1103/PHYSREVB.1.278
Jun-ichi Nakano, Yōichi Shiozaki, Eiji Nakamura, X-Ray Structural Study of KD2PO4 at Room Temperature Journal of the Physical Society of Japan. ,vol. 34, pp. 1423- 1423 ,(1973) , 10.1143/JPSJ.34.1423
W. J. Hay, R. J. Nelmes, Structural studies of CsD2AsO4 in the paraelectric phase and the ferroelectric phase Ferroelectrics. ,vol. 14, pp. 599- 600 ,(1976) , 10.1080/00150197608236677
N. S. J. Kennedy, R. J. Nelmes, F. R. Thornley, K. D. Rouse, Recent structural studies of the KH2PO4-KD2PO4 system Ferroelectrics. ,vol. 14, pp. 591- 593 ,(1976) , 10.1080/00150197608236675
W F Kuhs, R J Nelmes, J E Tibballs, The proton distribution in KDP above Tc Journal of Physics C: Solid State Physics. ,vol. 16, ,(1983) , 10.1088/0022-3719/16/29/002
P. S. Peercy, Observation of an Underdamped "Soft" Mode in Potassium Dihydrogen Phosphate Physical Review Letters. ,vol. 31, pp. 379- 382 ,(1973) , 10.1103/PHYSREVLETT.31.379