Thermodynamics of small electron-bound water clusters
作者：
DOI: 10.5012/BKCS.2003.24.6.802
关键词: Solvated electron 、 Trimer 、 Science, technology and society 、 Water cluster 、 Pentamer 、 Thermodynamics 、 Electron 、 Bound water 、 Entropy (order and disorder) 、 Chemistry
摘要: Center for Superfunctional Materials, Department of Chemistry, Pohang University Science and Technology, 790-784, KoreaReceived April 24, 2003The relative stabilities weak binding clusters are sensitive to temperature due the entropy effect. Thus,here we report significant changes in between two low-energy electron-water trimerstructures those three pentamer structures, as temperatureincreases. The trimer show structural around 200 K.Key Words : Solvated electron, Electron-bound water cluster, Electron-water clusters, Thermodynamics,Vertical-electron detachment energyIntroductionAs is most important solvent, electron-waterclusters have been an interesting subject physics,chemistry biochemistry.
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