Microwave-Assisted Conversion of Levulinic Acid to γ-Valerolactone Using Low-Loaded Supported Iron Oxide Nanoparticles on Porous Silicates

作者: Alfonso Yepez , Sudipta De , Maria Climent , Antonio Romero , Rafael Luque

DOI: 10.3390/APP5030532

关键词: Iron oxide nanoparticlesFormic acidLevulinic acidHydrogenCatalysisMetalIron oxideMaterials scienceInorganic chemistryNoble metal

摘要: The microwave-assisted conversion of levulinic acid (LA) has been studied using low-loaded supported Fe-based catalysts on porous silicates. A very simple, productive, and highly reproducible continuous flow method used for the homogeneous deposition metal oxide nanoparticles silicate supports. Formic was as a hydrogen donating agent hydrogenation LA to effectively replace high pressure H2 mostly reported conversion. Moderate achieved in case non-noble metal-based iron catalysts, with significant potential further improvements compete noble catalysts.

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