Asymmetric synthesis of functionalized tertiary homoallyl alcohols by diastereoselective allylation of chiral .alpha.-keto amides derived from (S)-proline esters: control of stereochemistry based on saturated coordination of Lewis acid

作者： Kenso Soai , Miyuki Ishizaki

关键词: Stereochemistry 、 Acid catalysis 、 Lactone 、 Lewis acids and bases 、 Enantioselective synthesis 、 Asymmetric induction 、 Solvent effects 、 Chemistry 、 Alcohol 、 Proline

摘要: Allylation des phenyloxalyl-1 prolinates par allyl-silanes, stannanes et magnesium bromure en presence d'acides de Lewis (induction asymetrique-1,4)

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Asymmetric synthesis of functionalized tertiary homoallyl alcohols by diastereoselective allylation of chiral .alpha.-keto amides derived from (S)-proline esters: control of stereochemistry based on saturated coordination of Lewis acid

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Asymmetric synthesis of functionalized tertiary homoallyl alcohols by diastereoselective allylation of chiral .alpha.-keto amides derived from (S)-proline esters: control of stereochemistry based on saturated coordination of Lewis acid

来源期刊

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