Structural Features of Monomeric Octahedral Monooxo d2-Renium(V) Complexes with Oxygen Atoms of O,N Bidentate-Chelating Ligands (Ln): 2. [ReO(Ln)(Lmono)3] Complexes with Six- and Seven-Membered Chelate Rings ReNC3O and ReNC4O
作者： V. S. Sergienko , A. V. Churakov
DOI: 10.1134/S0036023618060219
关键词: Crystallography 、 Octahedron 、 Cis–trans isomerism 、 Denticity 、 Chelation 、 Monomer 、 Ligand 、 Halide 、 Oxygen atom 、 Chemistry 、 Inorganic chemistry
摘要: Structural features of 26 mononuclear octahedral monooxo d2-Re(V) complexes with singly charged oxygen atoms bidentate-chelating (O,N) ligands (Ln), namely, [ReO(Ln)(Lmono)3] (where Lmono stands for a monodentate ligand) containing six- and seven-membered chelate rings ReNC3O ReNC4O, are considered. The O(Ln), one exception, in the trans positions to O(oxo). In [ReO(OPPh3)Cl2(L35)], position oxo ligand is occupied by neutral atom OPPh3. [ReO(Hal)2(Ln)(Lmono)] [(Lmono = PPh3, AsPPh3, OPPh3)] structures, two geometric isomers exist: halide either cis- or each other.
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sci-hub.se 参考文章(28)
Xiaoyuan Chen, Frank J Femia, John W Babich, Jon Zubieta, The syntheses and structures of '3+2' and '2+2+1' oxorhenium mixed-ligand complexes employing 8-hydroxy-5-nitroquinoline as the bidentate N,O donor ligand. Inorganica Chimica Acta. ,vol. 308, pp. 80- 90 ,(2000) , 10.1016/S0020-1693(00)00218-8
Maya Shivakumar, Sangeeta Banerjee, Mahua Menon, Animesh Chakravorty, SYNTHESIS AND X-RAY CRYSTAL STRUCTURE OF AN OXORHENIUM(V) COMPLEX WITH A DOUBLE SCHIFF BASE Inorganica Chimica Acta. ,vol. 275, pp. 546- 551 ,(1998) , 10.1016/S0020-1693(97)06071-4
T. I. A. Gerber, D. Luzipo, P. Mayer, Oxorhenium(V) complexes containing bidentate N,O-donor ligands of the pyridyl type Journal of Coordination Chemistry. ,vol. 59, pp. 1521- 1526 ,(2006) , 10.1080/00958970500537754
T.I.A. Gerber, D. Luzipo, P. Mayer, A monooxorhenium(V) complex with an unusually long Re=O bond: the structure of [ReOI2(ame)(PPh3)] (Hame=2-(2-aminophenyl)ethanol) Journal of Coordination Chemistry. ,vol. 57, pp. 1345- 1349 ,(2004) , 10.1080/00958970412331303868
E.M. Shustorovich, M.A. Porai-Koshits, Yu.A. Buslaev, The mutual influence of ligands in transition metal coordination compounds with multiple metal-ligand bonds Coordination Chemistry Reviews. ,vol. 17, pp. 1- 98 ,(1975) , 10.1016/S0010-8545(00)80300-8
Mahdi M. Abu-Omar, Saeed I. Khan, Molecular Rhenium(V) Oxotransferases: Oxidation of Thiols to Disulfides with Sulfoxides. The Case of Substrate-Inhibited Catalysis. Inorganic Chemistry. ,vol. 37, pp. 4979- 4985 ,(1998) , 10.1021/IC980348J
Smita Majumder, Arnab Bhattacharya, Jnan Prakash Naskar, Partha Mitra, Shubhamoy Chowdhury, An oxorhenium(V) Schiff-base complex: Synthesis, characterisation, structure, spectroscopic and electrochemical aspects Inorganica Chimica Acta. ,vol. 399, pp. 166- 171 ,(2013) , 10.1016/J.ICA.2013.01.018
G. Bandoli, A. Dolmella, T.I.A. Gerber, D. Mpinda, J. Perils, J.G.H. du Preez, Complexes of oxorhenium(V) with aromatic 2-amino-alcohols Journal of Coordination Chemistry. ,vol. 55, pp. 823- 833 ,(2002) , 10.1080/0095897022000001575
M. Sacerdoti, V. Bertolasi, G. Gilli, A. Duatti, The structure of trans-dibromooxo(N-phenylsalicylideneaminato)(triphenylphosphine)rhenium(V), form II (triclinic), [ReBr2(C13H10NO)O{P(C6H5)3}] Acta Crystallographica Section C-crystal Structure Communications. ,vol. 40, pp. 968- 970 ,(1984) , 10.1107/S0108270184006442
T.I.A Gerber, D Luzipo, P Mayer, The reaction of the cis-dioxorhenium(V) core with N,O-donor ligands: mono and bidentate coordination of 3-methyl-2-aminophenol Inorganica Chimica Acta. ,vol. 357, pp. 429- 435 ,(2004) , 10.1016/J.ICA.2003.06.010