Equilibrium, kinetic and isotherm of some metal ion biosorption

作者: Mehrorang Ghaedi , Shaaker Hajati , Farahnaz Karimi , Behnaz Barazesh , Gholamreza Ghezelbash

DOI: 10.1016/J.JIEC.2012.11.021

关键词: Freundlich equationEndothermic processBiosorptionIonMetal ions in aqueous solutionTrichoderma reeseiMetalInorganic chemistryChemistryLangmuirChromatography

摘要: Trichoderma reesei was used as a biosorbent for the removal of Co2+, Cu2+, Ni2+, Pb2+ and Zn2+ ions. The influence factors such pH, mass biomass, contact time temperature on biosorption efficiency optimized. To calculate isotherm parameters ions at optimized conditions, experimental equilibrium data were fitted to Langmuir Freundlich models. calculated thermodynamic parameters, ΔG°, ΔH° ΔS° showed that onto T. biomass feasible, spontaneous endothermic conditions. results kinetic analysis selected metal obeys pseudo second order kinetics.

参考文章(32)
Gabriela Huamán Pino, Luciana Maria Souza de Mesquita, Mauricio Leonardo Torem, Gustavo Adolfo Saavedra Pinto, Biosorption of cadmium by green coconut shell powder Minerals Engineering. ,vol. 19, pp. 380- 387 ,(2006) , 10.1016/J.MINENG.2005.12.003
Chilton Ng, Jack N Losso, Wayne E Marshall, Ramu M Rao, Freundlich adsorption isotherms of agricultural by-product-based powdered activated carbons in a geosmin–water system Bioresource Technology. ,vol. 85, pp. 131- 135 ,(2002) , 10.1016/S0960-8524(02)00093-7
Asma Saeed, Muhammed Iqbal, M Waheed Akhtar, None, Removal and recovery of lead(II) from single and multimetal (Cd, Cu, Ni, Zn) solutions by crop milling waste (black gram husk). Journal of Hazardous Materials. ,vol. 117, pp. 65- 73 ,(2005) , 10.1016/J.JHAZMAT.2004.09.008
Saima Q. Memon, Najma Memon, S.W. Shah, M.Y. Khuhawar, M.I. Bhanger, Sawdust--a green and economical sorbent for the removal of cadmium (II) ions. Journal of Hazardous Materials. ,vol. 139, pp. 116- 121 ,(2007) , 10.1016/J.JHAZMAT.2006.06.013
Gülten Atun, Tuba Sismanoglu, Adsorption of 4,4’ ‐ iso propylidene diphenol and diphenylolpropane 4,4’ dioxyaceticacid from aqueous solution on kaolinite Journal of Environmental Science and Health Part A-toxic\/hazardous Substances & Environmental Engineering. ,vol. 31, pp. 2055- 2069 ,(1996) , 10.1080/10934529609376474
K. Vijayaraghavan, K. Palanivelu, M. Velan, Biosorption of copper(II) and cobalt(II) from aqueous solutions by crab shell particles. Bioresource Technology. ,vol. 97, pp. 1411- 1419 ,(2006) , 10.1016/J.BIORTECH.2005.07.001
M MARTINEZ, N MIRALLES, S HIDALGO, N FIOL, I VILLAESCUSA, J POCH, Removal of lead(II) and cadmium(II) from aqueous solutions using grape stalk waste. Journal of Hazardous Materials. ,vol. 133, pp. 203- 211 ,(2006) , 10.1016/J.JHAZMAT.2005.10.030
Abdellah Aziz, Mohand Said Ouali, El Hadj Elandaloussi, Louis Charles De Menorval, Marc Lindheimer, None, Chemically modified olive stone: a low-cost sorbent for heavy metals and basic dyes removal from aqueous solutions. Journal of Hazardous Materials. ,vol. 163, pp. 441- 447 ,(2009) , 10.1016/J.JHAZMAT.2008.06.117