Distribution Equilibria of Eu(III) in the System: Bis(2-ethylhexyl)phosphoric Acid, Organic Diluent—NaCl, Lactic Acid, Polyaminocarboxylic Acid, Water

作者: P. R. Danesi , C. Cianetti , E. P. Horwitz

DOI: 10.1080/01496398208068555

关键词: DiluentInorganic chemistryAqueous solutionIonic strengthPhase (matter)ChemistryPhosphoric acidLactic acidMetalStability constants of complexes

摘要: Abstract The distribution equilibria of Eu3+ between aqueous phases containing lactic acid and N' -(2hydroxyethyl)ethylenediamine-N, N, -triacetic (HEDTA) or diethylenetriamine-N, N', N'' -penetaacetic (DTPA) at constant ionic strength (μ = 1.0), n-dodecane solutions HDEHP have been studied. formation constants the simple Eu-lactate complexes Eu-lactate-HEDTA mixed complex were evaluated from K d data. conclusion is reached that no coextracted into organic phase tracer metal concentrations. separation factors Eu3+, Pm3+, Am3+ in presence HEDTA.

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