作者: P. R. Danesi , C. Cianetti , E. P. Horwitz
DOI: 10.1080/01496398208068555
关键词: Diluent 、 Inorganic chemistry 、 Aqueous solution 、 Ionic strength 、 Phase (matter) 、 Chemistry 、 Phosphoric acid 、 Lactic acid 、 Metal 、 Stability constants of complexes
摘要: Abstract The distribution equilibria of Eu3+ between aqueous phases containing lactic acid and N' -(2hydroxyethyl)ethylenediamine-N, N, -triacetic (HEDTA) or diethylenetriamine-N, N', N'' -penetaacetic (DTPA) at constant ionic strength (μ = 1.0), n-dodecane solutions HDEHP have been studied. formation constants the simple Eu-lactate complexes Eu-lactate-HEDTA mixed complex were evaluated from K d data. conclusion is reached that no coextracted into organic phase tracer metal concentrations. separation factors Eu3+, Pm3+, Am3+ in presence HEDTA.